Oxidation of Monoterpenes Catalysed by a Water‐Soluble Mn        <sup >IIIIII        PEG‐Porphyrin in a Biphasic Medium

摘要

Abstract > It is well established that the transformation of abundant and cheap natural products, such as terpenoids, can produce other more valuable compounds. Thymoquinone, which has a commercial value significantly higher than that of its precursors, can be obtained by oxidation of carvacrol and thymol. In this work, a new water‐soluble Mn III PEG‐porphyrin is reported as catalyst in a water/hexane (1:1) biphasic medium for the oxidation of carvacrol and thymol into thymoquinone. The reactions were performed using tert ‐butyl hydroperoxide as oxidant in the presence of ammonium acetate as co‐catalyst, reaching 94 and 78?% of conversion after 5?h of reaction for thymol and carvacrol, respectively. Experiments with oregano essential oil as substrate revealed selective transformation of thymol and carvacrol into thymoquinone. The main advantage of this biphasic system based on a water‐soluble catalyst and on substrates and products soluble in hexane, is the straightforward isolation, recovery and recycling of the catalyst by simple phase separation. Recycling studies of the Mn III PEG‐porphyrin using thymol as substrate showed high conversion values throughout four catalytic cycles. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 很好地确定，丰富和廉价的天然产品（如Terpenoids）的转化可以产生其他更有价值的化合物。具有显着高于其前体的商业价值的胸腺量可以通过氧化碱和胸腺酚氧化来获得。在这项工作中，一个新的水溶性Mn iii </ sup> 在水/己烷（1：1）双相培养基中，将PEG-卟啉作为催化剂报道，用于氧化碳酸和百里酚进入胸腺量。使用反应使用 tert </ i> - 氢氧化氧化钠作为氧化剂在乙酸铵作为助催化剂存在，达到94％和78〜78〜78〜78〜78〜78〜78〜78.分别在5〜H的反应后转化率。用牛至精油作为基质的实验显示晶醇和碳酸氯醌的选择性转化。该双相系统基于水溶性催化剂和溶于己烷的产品的主要优点是通过简单的相分离直接隔离，回收和再循环催化剂。锰的回收研究 iii </ sup> 使用晶醇作为基质的PEG-卟啉在整个四个催化循环中显示出高转化值。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" > 著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16041/'>《ChemCatChem 》</a> <b style="margin: 0 2px;">|</b><span>2018年第13期</span><b style="margin: 0 2px;">|</b> <span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li> <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span> <a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学 ;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=biphasic catalysis&option=203" rel="nofollow">biphasic catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=manganese&option=203" rel="nofollow">manganese;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=monoterpenes&option=203" rel="nofollow">monoterpenes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxidation&option=203" rel="nofollow">oxidation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=porphyrins&option=203" rel="nofollow">porphyrins;</a> </p> <div class="translation"> 机译：双相催化;锰;单点;氧化;卟啉; 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王金渡&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王金渡</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=冯建&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,冯建</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨朝芬&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨朝芬</a> <span> <a href="/conference-cn-22303/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化学会第十届全国络合催化学术讨论会 </a> <span> <span> . 2007</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020311334259.html">烷氧基修饰的ZPS-PVPA和磺烃基修饰的ZnPSPPP轴向固载手性Salen Mn(III)催化剂的合成及其在非功能化烯烃的不对称环氧化反应中的应用</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王长炜&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王长炜</a> <span> . 2011</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061203984648.html">一种季铵盐型Mn(III)卟啉-SiO<Sub>2</Sub>催化剂的制备及应用</a> <b>[P]</b> . <span> 中国专利： CN108176413B </span> <span> . 2020.09.04</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120110660244.html">一种季铵盐型Mn(III)卟啉-SiO<Sub>2</Sub>催化剂的制备及应用</a> <b>[P]</b> . <span> 中国专利： CN108176413A </span> <span> . 2018-06-19</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130446457208.html">OXIDATIVE POLYMERIZATION OF NATURAL ORGANIC MATTER AND CO-POLYMERIZATION OF ORGANIC CONTAMINANTS CATALYSED IN PARTICULAR BY WATER SOLUBLE METAL-PORPHYRINS</a> <b>[P]</b> . <span> 外国专利：  WO0138454A3 </span> <span> . 2002-01-17</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：水溶性金属卟啉对特定有机物的氧化聚合及其对有机污染物的共聚合 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130448813558.html">Oxidative polymerization of natural organic matter and co-polymerization of organic contaminants catalysed in particular by water soluble metal-porphyrins</a> <b>[P]</b> . <span> 外国专利：  AU2837101A </span> <span> . 2001-06-04</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：天然有机物的氧化聚合和有机污染物的共聚合，尤其是由水溶性金属卟啉催化 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130448665886.html">OXIDATIVE POLYMERIZATION OF NATURAL ORGANIC MATTER AND CO-POLYMERIZATION OF ORGANIC CONTAMINANTS CATALYSED IN PARTICULAR BY WATER SOLUBLE METAL-PORPHYRINS</a> <b>[P]</b> . <span> 外国专利：  WO0138454A2 </span> <span> . 2001-05-31</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：水溶性金属卟啉对特定有机物的氧化聚合及其对有机污染物的共聚合 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022056898','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> 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Oxidation of Monoterpenes Catalysed by a Water‐Soluble Mn IIIIII PEG‐Porphyrin in a Biphasic Medium

摘要

Oxidation of Monoterpenes Catalysed by a Water‐Soluble Mn ^{IIIIII PEG‐Porphyrin in a Biphasic Medium}