A two-step method for preparing Li4Ti5O_(12)- graphene as an anode material for lithium-ion hybrid capacitors

摘要

Lithium-ion hybrid capacitors (LICs) are expected to fill the gap between lithium-ion batteries and electrochemical supercapacitors. In this paper, we synthesize Li4Ti5O12-graphene (LTO-G) by a two- step method and use it as the anode material in AC/LTO-G Li-ion hybrid capacitors. The LTO-G composite prepared by the two-step method shows the best electrochemical properties in various ways, and delivers a high specific capacity of 194 mA h g~(-1) at 0.1C, and 90 mA h g~(-1) at 28.6C. The AC/LTO-G capacitors can perform well between 1 and 2.5 V, and they deliver a reversible capacity of 80 mA h g~(-1) at 0.1C. The energy density based on the total active material for these capacitors is 15 W h kg~(-1) at 4000 Wkg~(-1) , and 30 W h kg~(-1) at 1000 W kg~(-1) . After 10 000 cycles, these capacitors still deliver an energy density higher than 22 W h kg~(-1) at 1000 W kg~(-1) . The highest energy density based the total mass of the device is 6.6 W h kg~(-1) and there is still much room for improvement, indicating that the LTO-G composite is a promising candidate anode material for Li-ion hybrid capacitors.