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Graphene oxide-polyaniline-polypyrrole nanocomposite for a supercapacitor electrode

机译:超级电容器电极的石墨烯氧化物 - 聚苯胺 - 聚吡咯纳米复合材料

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摘要

Graphene oxide based nanocomposites were prepared through the in situ polymerization of aniline and pyrrole to study the interaction of graphene oxide with polyaniline (PANI) and polypyrrole (PPy). Field emission scanning electron microscopy (FESEM) was used to study the surface morphology and transmission electron microscopy (TEM) for the qualitative understanding of the internal structure of PANI/PPy coating on GO. The chemical structures of composites were studied through X-ray photoelectron spectroscopy (XPS) analysis. It was observed that specific capacitance of PPy coated GO improved by similar to 122.73% compared to pristine GO. Moreover, the binding energy of polypyrrole-graphene oxide was found to be higher than polyaniline-graphene oxide because of the absence of oxygen containing functional groups. In addition, the storage capacity was effectively improved due to the synergistic effect of polypyrrole coating on graphene oxide.
机译:通过苯胺和吡咯的原位聚合制备石墨烯氧化物的纳米复合材料,以研究石墨烯与聚苯胺(PANI)和聚吡咯(PPY)的相互作用。 现场发射扫描电子显微镜(FeSEM)用于研究表面形态和透射电子显微镜(TEM),了解PANI / PPY涂层内部结构的定性识。 通过X射线光电子体光谱(XPS)分析研究了复合材料的化学结构。 观察到,与原始Go相比,PPY涂层的特定电容与122.73%相似。 此外,由于没有含氧的官能团,发现发现聚吡咯-氧化烯氧化物的结合能量高于聚苯胺 - 石墨烯氧化物。 此外,由于聚吡咯涂层在氧化铟烯涂层的协同作用,储存能力有效地改善。

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  • 来源
    《RSC Advances》 |2015年第4期|共6页
  • 作者单位

    Indian Inst Technol Dept Mech &

    Ind Engn Roorkee 247667 Uttar Pradesh India;

    Indian Inst Technol Dept Mech &

    Ind Engn Roorkee 247667 Uttar Pradesh India;

    Indian Inst Technol Dept Mech &

    Ind Engn Roorkee 247667 Uttar Pradesh India;

    Gyeongsang Natl Univ Dept Chem &

    Biol Engn Gajwa Dong 660701 Jinju South Korea;

    Gyeongsang Natl Univ Dept Chem &

    Biol Engn Gajwa Dong 660701 Jinju South Korea;

    Gyeongsang Natl Univ Dept Polymer Sci &

    Engn Gajwa Dong 660701 Jinju South Korea;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
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