Effects of solid loading on the rheological behaviors and mechanical properties of injection-molded alumina ceramics

摘要

In this work, alumina ceramics were prepared by injection molding. The effects of solid loading on the rheological behaviors of the feedstocks, as well as the resulting properties of the green bodies and sintered ceramics were investigated. It was found that the viscosity and stabilized torque values of the feedstocks increased with the increase of solids loading in the range of 48-54 vol.%. The feedstock with 54 vol.% alumina exhibited dilatant rheology behavior and high viscosity; however, the feedstocks with less than 52 vol.% alumina exhibited pseudoplastic rheology behavior. After removing the organic binder, the pre-sintered bodies with high alumina content had smaller most frequent pore diameter, which was beneficial to sintering densification. With an increase in solid loading, the density of the green and sintered bodies increased and the shrinkage decreased. The green and sintered bodies at the solid loading of 52 vol.% presented uniform, compact microstructures, and possessed the highest bending strength of 25 MPa and 440 MPa, respectively. (C) 2018 Elsevier B.V. All rights reserved.