High-performance nitrogen doped carbon quantum dots: Facile green synthesis from waste paper and broadband photodetection by coupling with ZnO nanorods

摘要

High-performance N-doped carbon quantum dots (NCQDs) were synthesized by a proposed green route based on hydrothermal treatments using waste paper and urea as C and N sources. The single-crystalline NCQDs demonstrated strong blue-green luminescence with the maximum intensity enhancement of 6.5 times when compared with undoped CQDs under UV and visible light excitations. XPS spectra results suggested that the enhanced photoluminescence might be attributed to pyridinic N, which could be controlled by adjusting hydrothermal temperature, time, and urea concentration. The NCQDs having excellent optoelectronic properties were fabricated into broadband photodetectors by incorporating ZnO nanorod arrays. Owing to the NCQDs, the detectors demonstrated broadband photoresponse with significantly enhanced photoresponsivity, faster response, and better sensitivity in visible range. The work provides a low-cost, environment friendly route to fabricate excellent NCQD-based broadband photodetectors for various technological applications. (C) 2019 Elsevier B.V. All rights reserved.