Comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors

摘要

Biodegradable solid polymer electrolyte (SPE) systems composed of hydroxylethyl cellulose blended with copper(II) oxide (CuO) and yttrium(III) oxide (Y2O3) nanoparticles as fillers, magnesium trifluoromethane sulfonate salt, and 1-ethyl-3-methylimidazolium trifluoromethane sulfonate ionic liquid were prepared, and the effects of the incorporation of CuO and Y2O3 nanoparticles on the performance of the SPEs for electric double-layer capacitors (EDLCs) were compared. The X-ray diffraction results reveal that the crystallinity of the SPE complex decreased upon inclusion of the Y2O3 nanoparticles compared to CuO nanoparticles; this led to a higher ionic conductivity of the Y2O3-based SPE [(3.08 +/- 0.01) x10(-4) S/cm] as compared to CuO [(2.03 +/- 0.01) x10(-4) S/cm]. The EDLC performances demonstrated that the cell based on CuO nanoparticles had superior performance in terms of the specific capacitance, energy, and power density compared to the Y2O3-nanoparticle-based cell. However, Y2O3-nanoparticle-based cell displayed a high cyclic retention (91.32%) compared to the CuO-nanoparticle-based cell (80.46%) after 3000 charge-discharge cycles. (C) 2016 Wiley Periodicals, Inc.