A study of the effect of carbon characteristics on capacitive deionization (CDI) performance

摘要

In an attempt to improve the capacitive deionization (CDI) performance and develop an efficient CDI electrode material, the effect of carbon characteristics on CDI was investigated. Activated carbon (AC) and ordered mesoporous carbon (OMC) materials synthesized by template method were used for the electrode manufacture. The capacitive deionization performance of AC and OMC based electrodes was investigated and compared. We found that when the specific surface areas of AC materials increased from 712 to 1347 m(2)/g, the electrosorption capacities of AC electrodes increased slightly from 9.43 to 10.14 mg/g. The characteristics of OMC materials can be optimized by the adjustment of the mesoporous silica beads template proportion, resulting in a maximum average pore size of 11.35 nm and total pore volume of 2.101 cm(3)/g. The optimum electrosorption capacity obtained with OMC4 electrode was 10.83 mg/g, which was not only higher than that of AC electrodes, but obviously higher than the values of most carbon-based electrodes in other studies. In conclusion, these results provide important insights into the effect of carbon characteristics on capacitive deionization and suggest that OMC synthesized by template method could be a promising carbon material for the CDI electrode manufacture.