Slow magnetic relaxation in a {(CoCo2III)-Co-II} complex containing a high magnetic anisotropy trigonal bipyramidal Co-II centre

Collet Alexandra; Craig Gavin A.; Ojea Maria Jose Heras; Bhaskaran Lakshmi; Wilson Claire; Hill Stephen; Murrie Mark

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Slow magnetic relaxation in a {(CoCo2III)-Co-II} complex containing a high magnetic anisotropy trigonal bipyramidal Co-II centre

机译：含有高磁各向异性三角形双滤网CO-II中心的{（COCO2IIII）-CO-II}复合物中的慢性磁性松弛

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We report a trinuclear mixed-valence {(CoCo2III)-Co-II} complex, where the Co-II centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.

机译：我们报告了三个清晰的混合价{（Coco2iII）-Co-II}复合物，其中Co-II中心采用Trigonal的双滤网几何形状，导致大，易平面磁各向异性和现场诱导的慢磁性放松，与拉曼 - 般的放松过程。

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《Dalton transactions: An international journal of inorganic chemistry 》 |2018年第28期| 共4页
作者
Collet Alexandra; Craig Gavin A.; Ojea Maria Jose Heras; Bhaskaran Lakshmi; Wilson Claire; Hill Stephen; Murrie Mark;
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Univ Glasgow WestCHEM Sch Chem Univ Ave Glasgow G12 8QQ Lanark Scotland;

Univ Glasgow WestCHEM Sch Chem Univ Ave Glasgow G12 8QQ Lanark Scotland;

Univ Glasgow WestCHEM Sch Chem Univ Ave Glasgow G12 8QQ Lanark Scotland;

Florida State Univ Dept Phys Tallahassee FL 32310 USA;

Univ Glasgow WestCHEM Sch Chem Univ Ave Glasgow G12 8QQ Lanark Scotland;

Florida State Univ Dept Phys Tallahassee FL 32310 USA;

Univ Glasgow WestCHEM Sch Chem Univ Ave Glasgow G12 8QQ Lanark Scotland;

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正文语种 eng
中图分类化学 ; 无机化学 ;
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1. Slow magnetic relaxation in a {(CoCo2III)-Co-II} complex containing a high magnetic anisotropy trigonal bipyramidal Co-II centre [J] . Collet Alexandra, Craig Gavin A., Ojea Maria Jose Heras, Dalton transactions: An international journal of inorganic chemistry . 2018 ,第28期

机译：含有高磁各向异性三角形双滤网CO-II中心的{（COCO2IIII）-CO-II}复合物中的慢性磁性松弛
2. Slow magnetic relaxation and water oxidation activity of dinuclear (CoCoIII)-Co-II and unique triangular (CoCoCIII)-Co-II-C-II mixed-valence complexes [J] . Dalton transactions: An international journal of inorganic chemistry . 2020 ,第19期

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3. Sizeable Effect of Lattice Solvent on Field Induced Slow Magnetic Relaxation in Seven Coordinated Co-II Complexes [J] . Mondal Arpan, Kharwar Ajit Kumar, Konar Sanjit Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019 ,第16期

机译：晶格溶剂对七种协调二氧化硅络合物诱导慢磁性松弛的相当大
4. Field-induced Slow Magnetic Relaxation in Tetrahedral Cobalt(II)Complexes with Halide Donors [C] . RyojiMitsuhashi, Satoshi Hosoya, Takayoshi Suzuki 日本化学会春季年会 . 2020

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5. Magnetic properties and reactivity studies of families of trigonal bipyramidal cyanide clusters and their extended structures [D] . Funck, Kristen Elise 2010

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6. In-depth investigation of large axial magnetic anisotropy in monometallic 3d complexes using frequency domain magnetic resonance and ab initio methods: a study of trigonal bipyramidal Co(ii) [O] . Moya A. Hay, Arup Sarkar, Gavin A. Craig, 2019

机译：使用频域磁共振和从头算方法深入研究单金属3d配合物中的大轴向磁各向异性：三角双锥体Co（ii）的研究
7. In-depth investigation of large axial magnetic anisotropy in monometallic 3d complexes using frequency domain magnetic resonance and ab initio methods: a study of trigonal bipyramidal Co(ii) [O] . Moya A. Hay, Arup Sarkar, Gavin A. Craig, 2019

机译：使用频域磁共振和AB Initio方法深入研究单金属3D复合物中的大型轴向磁各向异性：Tigonal Bipyramidal Co（II）的研究

Slow magnetic relaxation in a {(CoCo2III)-Co-II} complex containing a high magnetic anisotropy trigonal bipyramidal Co-II centre

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