Phototriggered Ketone Formation from an Aminocyclopropenone and a Carboxylic Acid

摘要

A novel phototriggered functionalization reaction of a carboxylic acid using an aminocyclopropenone has been developed. Irradiation of an aminocyclopropenone and carboxylic acid mixture generated ketones that possessed substituents from both the carboxylic acid and the aminocyclopropenone. This reaction occurred through two distinct photo-triggered processes. Using this reaction, substituents in an aminocyclopropenone can containing molecule. be be connected with a carboxylic acid containing molecule.