Creating highly wettable paper towel-like aluminum surfaces through tuned bulk micro-manufacturing

摘要

The contact angle (CA) of a water droplet on the polished aluminum surfaces is usually between 60A degrees and 90A degrees. This paper discusses a tuned bulk micro-manufacturing approach for transforming the surface topology of aluminum simultaneously at the micro- and nano-length scales, thereby significantly influencing its wetting characteristics. The approach is cheap, easy to implement, and scalable. The treated aluminum surfaces appeared like roughly polished surfaces at the macroscale and were found to be robust and non-toxic. They exhibited a paper towel effect by showing extreme surface wettability (CA of zero) to many industrial liquids, i.e., wetting on these surfaces is only a function of the surface roughness but not the fluid type. This extreme wetting ability to multiple liquids (or ultra-omniphilicity) was generated by sequentially creating a sub-surface micro- and nano-cavity architecture with nano-cavities within the embryos of micro-cavities interconnected by a network of micro-grooves.