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Water as a hydrogen source in palladium-catalyzed reduction and reductive amination of nitroarenes mediated by diboronic acid

机译:水作为钯催化的氢气源的氢气源,二硼酸介导的硝基甲烷的还原胺化

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摘要

Abstract An unprecedented palladium-catalyzed chemoselective reduction and reductive amination of nitroarenes with water as a hydrogen source mediated by diboronic acid have been discovered. A series of aryl amines containing various reducible functional groups were obtained in good to excellent yields. Graphical abstract Display Omitted ]]>
机译:<![CDATA [ 抽象 作为由diboronic酸介导的氢源的氢气源是前所未有的钯催化的化学选择性和硝基拉酮的还原胺化被发现了。良好地获得含有各种可还原官能团的一系列芳基胺。 图形抽象 显示省略 ]]>

著录项

  • 来源
    《Tetrahedron》 |2017年第28期|共7页
  • 作者单位

    Hubei Key Laboratory of Natural Products Research and Development College of Biological and Pharmaceutical Sciences China Three Gorges University;

    Hubei Key Laboratory of Natural Products Research and Development College of Biological and Pharmaceutical Sciences China Three Gorges University;

    Hubei Key Laboratory of Natural Products Research and Development College of Biological and Pharmaceutical Sciences China Three Gorges University;

    Hubei Key Laboratory of Natural Products Research and Development College of Biological and Pharmaceutical Sciences China Three Gorges University;

    Hubei Key Laboratory of Natural Products Research and Development College of Biological and Pharmaceutical Sciences China Three Gorges University;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

    Reduction; Reductive amination; Nitroarenes; Diboronic acid; Hydrogen source;

    机译:减少;还原胺化;硝基酮;脱硼酸;氢气源;

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