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首页> 外文期刊>Physical chemistry chemical physics: PCCP >Biased continuous-time random walks for ordinary and equilibrium cases: facilitation of diffusion, ergodicity breaking and ageing
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Biased continuous-time random walks for ordinary and equilibrium cases: facilitation of diffusion, ergodicity breaking and ageing

机译:用于普通和平衡案例的偏见连续时间随机散步:促进扩散,遍历性破碎和老化

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摘要

We examine renewal processes with power-law waiting time distributions (WTDs) and non-zero drift via computing analytically and by computer simulations their ensemble and time averaged spreading characteristics. All possible values of the scaling exponent alpha are considered for the WTD psi(t) similar to 1/t(1+alpha). We treat continuous-time random walks (CTRWs) with 0 alpha 1 for which the mean waiting time diverges, and investigate the behaviour of the process for both ordinary and equilibrium CTRWs for 1 alpha 2 and alpha 2. We demonstrate that in the presence of a drift CTRWs with alpha 1 are ageing and non-ergodic in the sense of the non-equivalence of their ensemble and time averaged displacement characteristics in the limit of lag times much shorter than the trajectory length. In the sense of the equivalence of ensemble and time averages, CTRW processes with 1 alpha 2 are ergodic for the equilibrium and non-ergodic for the ordinary situation. Lastly, CTRW renewal processes with alpha 2-both for the equilibrium and ordinary situation-are always ergodic. For the situations 1 alpha 2 and alpha 2 the variance of the diffusion process, however, depends on the initial ensemble. For biased CTRWs with alpha 1 we also investigate the behaviour of the ergodicity breaking parameter. In addition, we demonstrate that for biased CTRWs the Einstein relation is valid on the level of the ensemble and time averaged displacements, in the entire range of the WTD exponent alpha.
机译:我们通过分析和计算机模拟它们的集合和时间平均扩展特性,通过计算借助幂等候时间分布(WTD)和非零漂移来检查续订流程和非零漂移。缩放指数alpha的所有可能值都被认为是类似于1 / t(1 + alpha)的WTD PSI(T)。我们将连续时间随机散步(CTRW)与0& alpha&图1所示的平均等待时间偏离,并研究普通和平衡CtrW的过程的行为为1& alpha& 2和alpha&我们证明在漂移CTRW的存在中,α& 1是衰老和非遍历,其集合和时间平均位移特性的滞后时间比轨迹长度短的极限。在集合和时间平均值的等价的意义上,CTRW进程具有1& alpha& 2对于普通情况来说是平衡和非遍历的ergodic。最后,使用alpha&gt的Ctrw续订进程; 2-均衡和普通情况 - 始终是遍历。对于情况1& alpha& 2和alpha& [但是,扩散过程的方差取决于初始合奏。对于具有alpha&gt的偏置的CTRW。 1我们还研究了遍历了遍历性破碎参数的行为。此外,我们证明,对于偏置的CTRW,EINSTEIN关系在WTD指数alpha的整个范围内有效地对集合和时间平均位移的水平。

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