Multi-branched gold nanostars with fractal structure for SERS detection of the pesticide thiram

摘要

AbstractThe surface-enhanced Raman scattering (SERS) activity of multi-branched gold nanostars with fractal structure has been investigated for trace detection of pesticide thiram. Raman spectrum results show that the gold nanostars substrate can produce about 102fold stronger signal than the thiram alone with the thiram concentration increase of 103times and 1.4 fold stronger signal than the gold nanostars without fractal feature. In the detection procedure, the most prominent SERS peak at 1376cm?1has been chosen to characterize and quantify the concentration of thiram. Experimental results indicate this Raman substrate based on fractal gold nanostars exhibits excellent selective probing performance for thiram with a detection limit as low as 10?10M in solution and 0.24ng/cm2in apple peels. Interference experiment results show that the effects from the interfering pesticides could be neglected in the detection procedure. Therefore, the gold nanostars as a SERS substrate have excellent sensitivity and selectivity.Graphical AbstractThe surface-enhanced Raman scattering (SERS) substrate based on multi-branched gold nanostars with fractal structure exhibits excellent selective probing performance for thiram.