In situ formation of Co3O4 hollow nanocubes on carbon cloth-supported NiCo2O4 nanowires and their enhanced performance in non-enzymatic glucose sensing

摘要

Diabetes is a chronic disease that can seriously affect human health. Therefore it is important to develop a rapid and highly sensitive enzyme-free glucose sensor to aid the treatment of diabetes. In this work, homogeneous NiCo2O4 nanowire arrays were synthesized in an orderly fashion on flexible carbon cloth (CC) by a facile hydrothermal method. Then well-structured zeolitic imidazolate framework (ZIF-67) nanocubes were grown in situ on the as-prepared NiCo2O4 nanowires to form a hybrid nanoarchitecture. The hierarchical structure was transformed into a Co3O4/NiCo2O4/CC composite after annealing in the air. The as-prepared electrode was put into 0.1 M NaOH, and cyclic voltammetry and amperometry were employed to investigate its electrocatalytic properties at room temperature. It was found that the Co3O4/NiCo2O4/CC electrode exhibited outstanding sensing properties towards glucose, including terrific sensitivity (12.835 mA mM(-1) cm(-2)), a wide linear range (from 1 mu M to 1.127 mM), a low detection limit (0.64 mu M) and a fast response time (within 2 s). In addition, it also had excellent selectivity, reproducibility and stability. The improvement in enzyme-free glucose sensing, in addition to the high porosity and large specific surface area of metal organic framework-derived Co3O4 hollow nanocubes, can be attributed to the NiCo2O4 nanowire arrays affording fast channels for electron transfer between CC and Co3O4. Accordingly, this method, which directly prepares hierarchical composite nanomaterials on a conductive substrate, may open up a new perspective for the enhancement of non-enzymatic glucose-sensing properties.