Copper‐Catalyzed Carbonylative Cross‐Coupling of Arylboronic Acids with NN ‐Chloroamines for the Synthesis of Aryl Amides

摘要

> A novel copper‐catalyzed carbonylative cross‐coupling between N ‐chloroamines and arylboronics acids has been developed. With copper(I) oxide as the catalyst, various desired amide compounds were produced in moderate to good yields. Functional groups such as iodide and alkene are tolerated. Notably, this is the first example of a copper‐catalyzed aminocarbonylation with N ‐chloroamines.