Effects of steam pretreatment on fouled membrane in chemical cleaning for flux recovery in drinking water treatment

摘要

This paper shows the possibility of using steam pretreatment to improve the efficiency of membrane recovery chemical cleaning. Before applying chemicals to clean a fouled membrane, steam pretreatment was employed to loosen the structure of the foulant layer and weaken the attachment of those foulants on the membrane. Although longer steam contact times would lead to even better cleaning efficiency, the steam pretreatment duration was limited to less than 2 min to maintain membrane integrity. When cleaning fouled membranes with 1 mol/L HCl, the cleaning efficiency without steam pretreatment went from 83.3 to 90.2% as cleaning time increased from 30 to 180 min. As for 90-s steam pretreatment, the cleaning efficiency showed high values of more than 93% regardless of cleaning time. When the concentration of HCl was decreased to 0.2 mol/L, the cleaning efficiencies with a 90-s steam pretreatment was 78.6% and 92.6% for relatively short cleaning times of 30 and 60 min, respectively; this is much higher than the 62.2% and 76.7% achieved when cleaning without steam pretreatment. In addition, when using alkaline solution as the cleaning chemical, similar results were obtained. This implies that the application of steam before chemical cleaning is effective in improving cleaning efficiency, and so, this technique has the potential to reduce the amount of cleaning chemical required for membrane recovery cleaning.