Ultrafine SnO 2 nanoparticles encapsulated in ordered mesoporous carbon framework for Li-ion battery anodes

摘要

Ultrafine SnO2particles are encapsulated in the hollow nanochannels of ordered mesoporous carbon (OMC) framework by simple infiltration of tin precursor and heat treatment. The SnO2@OMC anode delivers excellent cyclic stability with a reversible specific capacity of ～1000?mAh g?1after 100 cycles at 100?mA?g?1for Li-ion batteries (LIBs). It also presents an excellent rate performance with a specific capacity of 680?mA?g?1at a high current density of 500?mA?g?1. Several functional features and ameliorating geometries play positive roles in Li-storage performance and stability of the electrode. They include (i) the intimate electrical contacts between the SnO2nanoparticles and the walls of OMC channels to facilitate fast ion/electron transfer, (ii) the large surface area originating from the unique architecture of the composite, and (iii) the encapsulation of SnO2particles within the channels to suppress their volume expansion during charge/discharge cycles. The reversibility of the conversion reaction is also supported by the high Li-ion diffusion coefficient with enhanced electrochemical reaction kinetics. Based on the above findings, this work may offer new insights into the rational nanostructural design of electrode materials for high performance rechargeable batteries.