In-situ synthesis of hybrid nickel cobalt sulfide/carbon nitrogen nanosheet composites as highly efficient bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries

摘要

In this work, an in-situ synthetic, pyrolytic and carbonized method is elaborately demonstrated to prepare the nickel cobalt sulphide (NiCo2S4) nanoparticles (NPs)/carbon nitrogen nanosheets (CNNs) composites as a highly efficient bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries (ZABs). Specifically, the in-situ synthesized NiCo2S4 NPs confined in cages of CNNs create a well-defined electron transfer hetero-interface with more exposed active sites. The combined NiCo2S4 NPs with the CNNs generate a synergistic effect, which provides effective electron transfer pathways to enhance the electrocatalytic behaviors, yielding a more positive half-wave potential (0.83 V) for oxygen reduction reaction (ORR) and a lower overpotential (360 mV at 10 mA cm(-2)) for oxygen evolution reaction (OER). As a proof of concept, the equipped ZABs exhibit a high peak power density of 92 mW cm(-2) and a superior energy density of 1025 Wh kg(-1) with robust cycling stability over 1000 cycles for 180 h, which are better than that of a commercially available Pt/C-RuO2 catalyst. The findings highlight the practical viability of the NiCo2S4/CNNs composites in rechargeable ZABs and provide a new approach for the efficient synthesis of bifunctional oxygen electrocatalyst in the future. (C) 2020 Published by Elsevier Ltd.