Melting experiments on the Fe-C binary system up to 255 GPa: Constraints on the carbon content in the Earth's core

摘要

Phase relations, including the eutectic liquid composition in the Fe-C binary system, remain unclear under the core pressure range, which makes estimating the carbon budget in the Earth's core difficult. To explore this issue, we have conducted melting and subsolidus experiments on Fe-C alloys in a diamond anvil cell up to 255 GPa. Textural and compositional characterizations of quenched samples show that carbon concentration in the eutectic liquid slightly decreases with increasing pressure and is about 3 wt.% at the inner core boundary (ICB) pressure. The solubility of carbon in solid Fe is found to be almost constant at similar to 1.0 wt.%. In situ X-ray diffraction data indicate that Fe forms eutectic melting with Fe3C to 203 GPa and with Fe7C3 at 255 GPa.