Synthesis, structure and characterization of a new highly porous zirconium-based metal-organic frameworks

摘要

A new highly porous zirconium-based metal-organic frameworks MOF-1 was constructed from a vinyl tetracarboxylic ligand and inorganic building blocks [Zr6O4(OH)(4)(CO2)(12)] under solvothermal conditions. MOF-1 crystallize in the cubic Pm-3m space group with a unique ftw topology. Additionally, MOF-1 performs a prominently chemical, thermal stability and high nitrogen absorption.