Mechanistic study on iron(II)‐mediated direct arylation of benzene with chlorobenzene

机译：铁（II）型铁（II）型苯二苯二苯二苯并苯二甲酸苯的机械研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Abstract > Density functional theory calculations on the reaction mechanisms of the direct arylation of benzene with chlorobenzene mediated by a series of low‐valent iron complexes, in which the Fe(II) center is surrounded by different electron‐donor ligands (acetate anion (OAc), baphophenanthroline (baph), 1,10‐phenanthroline (phen), and redox active ligand amidophenolate (ap)) using density functional theory. Fe(II) models, 1b Fe II (baph), 1p Fe II (phen), 1d Fe II (diimine), 2o Fe II (OAc) <sub>2</sub> , 2po Fe II (OAc)(phen), 2p Fe II (phen) <sub>2</sub> as well as 2a Fe II (ap) <sub>2</sub> were established. According to our calculations, 1b and 2a are promising candidates for the direct arylation transformation. The complexes under different ligands show their unique mechanism characteristics. Furthermore, a correlation has been established among the activation barriers, the energy gaps of frontier orbitals, the distortion energies, as well as the reaction enthalpies. The knowledge obtained herein not only deepens our mechanistic understanding of iron‐mediated direct arylation but may also provide guidance for the rational design of catalysts. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>摘要</标题> >密度函数理论计算对苯与a的氯苯直接芳基的反应机制的反应机制低价铁复合物系列，其中Fe（ii）中心被不同的电子 - 供体配体包围（醋酸阴离子（OAc），BaphoPhen蒽（Baph），1,10-菲咯啉（Phen），氧化还原活性配体酰胺苯甲酸酯（AP））使用密度泛函理论。 Fe（ii）型号， 1b </ b> Fe II </ sup>（乳酸）， 1p + fe II </ sup>（phen），<b > 1d </ b> Fe II </ sup>（二亚胺）， 2o </ b> Fe II </ sup>（OAc）<sub> 2 </ sub>，<b > 2PO </ b> Fe II </ sup>（OAc）（phen）， 2p + / b> Fe II </ sup>（phen）<sub> 2 </ sub>以及建立 2a </ b> fe ii </ sup>（ap）<sub> 2 </ sub>。根据我们的计算， 1b </ b>和 2a </ b>是直接芳基化转化的候选者。不同配体下的络合物显示出其独特的机制特性。此外，在激活屏障中建立了相关性，前沿轨道的能量间隙，失真能量以及反应焓。本文获得的知识不仅加深了对铁介导的直接芳基的机械理解，而且还可为催化剂的合理设计提供指导。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-21753/'>《International Journal of Quantum Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2019年第13期</span><b style="margin: 0 2px;">|</b><span>共13页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sun Xiaoli&option=202" target="_blank" rel="nofollow">Sun Xiaoli;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Geng Caiyun&option=202" target="_blank" rel="nofollow">Geng Caiyun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Jilai&option=202" target="_blank" rel="nofollow">Li Jilai;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute of Theoretical ChemistryJilin UniversityChangchun People's Republic of China;</p> <p>Institut für ChemieTechnische Universit?t BerlinBerlin Germany;</p> <p>Institute of Theoretical ChemistryJilin UniversityChangchun People's Republic of China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=arylation&option=203" rel="nofollow">arylation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=C‐C coupling&option=203" rel="nofollow">C‐C coupling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=computational chemistry&option=203" rel="nofollow">computational chemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=iron catalysis&option=203" rel="nofollow">iron catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ligand effect&option=203" rel="nofollow">ligand effect;</a> </p> <div class="translation"> 机译：芳基;C-C耦合;计算化学;铁催化;配体效果; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019755329.html">Mechanistic study on iron(II)‐mediated direct arylation of benzene with chlorobenzene</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sun Xiaoli&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sun Xiaoli,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Geng Caiyun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Geng Caiyun,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Jilai&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Li Jilai </a> <a href="/journal-foreign-21753/" target="_blank" rel="nofollow" class="tuijian_authcolor">International Journal of Quantum Chemistry .</a> <span>2019</span><span>,第13期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：铁（II）型铁（II）型苯二苯二苯二苯并苯二甲酸苯的机械研究</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704014011384.html">A mechanistic study on the catalytic combustion of benzene and chlorobenzene</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=de Jong V.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">de Jong V.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cieplik MK.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Cieplik MK.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Reints WA.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Reints WA.,</a> <a href="/journal-foreign-34045/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Catalysis .</a> <span>2002</span><span>,第2期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：苯和氯苯催化燃烧的机理研究</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019762639.html">Mechanistic study of solvent exchange reactions of manganese(II), iron(II), nickel(II), copper(II), and iron(III) ions in bulky 1,1,3,3-tetramethylurea (TMU) solvent by measurements of oxygen-17 NMR relaxation rates and chemical shifts: Complexation</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tanada K&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tanada K,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hashimoto A&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hashimoto A,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tsuji H&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tsuji H,</a> <a href="/journal-foreign-21965/" target="_blank" rel="nofollow" class="tuijian_authcolor">Inorganica Chimica Acta .</a> <span>2006</span><span>,第2期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过测量测量，锰（II），铁（II），铁（II），铁（II），镍（II），铜（II）和铁（III）离子（TMU）溶剂中的铁（III）离子（III）溶剂的机械研究氧气-17 NMR弛豫率和化学换档：络合</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-252588_thesis/0705010370091.html">Iron-Catalyzed Direct Arylation of 2-Arylpyridine Derivatives</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Naohiko Yoshikai&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Naohiko Yoshikai,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jakob Norinder&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jakob Norinder,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Arimasa Matsumoto&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Arimasa Matsumoto </a> <a href="/conference-foreign-252588/" target="_blank" rel="nofollow" class="tuijian_authcolor">Symposium on Organometallic Chemistry .</a> <span>2008</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：铁催化的2-芳基吡啶衍生物的直接芳基</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061197991.html">Palladium-Catalyzed Direct Functionalization of Aromatic Carbon-Hydrogen Bonds: Development of Methods for Direct Amination and Mechanistic Studies of Direct Arylation of Benzene and Pyridine N-Oxide.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tan, Yichen.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tan, Yichen. </a> <span>2013</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：钯催化芳香碳氢键的直接官能化：苯胺和吡啶N-氧化物的直接胺化方法的发展和直接胺化的机理研究。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040005824713.html">Mechanistic Studies on Direct Arylation of Pyridine N-Oxide: Evidence for Cooperative Catalysis between Two Distinct Palladium Centers</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yichen Tan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yichen Tan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fabiola Barrios-Landeros&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Fabiola Barrios-Landeros,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=John F. Hartwig&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">John F. Hartwig </a> <span>-1</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：机理研究吡啶N-氧化物的直接芳基：两种截然不同的钯中心之间证据协同催化</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000126952837.html">Electrophilic Substitution of Thiophenes with Arylpalladium(II) and Platinum(II) Complexes: Mechanistic Studies on Palladium-Catalyzed CH Arylation of Thiophenes</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Atsushi Sugie&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Atsushi Sugie,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hirotoshi Furukawa&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hirotoshi Furukawa,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yuji Suzaki&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yuji Suzaki,</a> <span>2009</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：芳基苯醚和铂（II）复合物的亲冠烯醇替代物：磷酸钯催化CH芳基的机械研究</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_acta-chimica-sinica_thesis/0201292740563.html">含烯烃配体的过渡金属卡宾配合物的研究 ⅩⅥ.丁二烯-和异戊二烯二羰基乙氧基(芳基)卡宾铁配合物的异构化产物与三苯膦和亚磷酸三苯酯的反应研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王天兰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王天兰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈家碧&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈家碧</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王绮文&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王绮文</a> <span> <a href="/journal-cn-53859/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学学报 </a> </span> <span> . 1991</span><span>,第3期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-organic-chemistry_thesis/0201298207879.html">羰基铁-硫酚-三乙胺反应体系的研究——(μ-酰基)(μ-苯硫)及(μ-σ,π-烯基)(μ-苯硫)六羰基二铁配合物的合成</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宋礼成&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 宋礼成</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘金亭&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘金亭</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王积涛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王积涛</a> <span> <a href="/journal-cn-15847/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 有机化学 </a> </span> <span> . 1989</span><span>,第1期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-university-science-technology-liaoning_thesis/0201285392718.html">由4,4′-二氰基二苯醚水解制取4,4′-二苯醚二甲酸的实验研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马有义&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 马有义</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李刚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李刚</a> <span> <a href="/journal-cn-4499/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 辽宁科技大学学报 </a> </span> <span> . 1990</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201296682822.html">含二羟基二苯酮系列热致液晶共聚酯的合成与表征──Ⅱ．含4，4＇－二羟基二苯酮，对苯二甲酸，对羟基苯甲酸，间苯二酚的共聚酯</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=董德文&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 董德文</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=倪玉山&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,倪玉山</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=池振国&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,池振国</a> <span> <a href="/journal-cn-56916/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高分子学报 </a> </span> <span> . 1996</span><span>,第2期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chemical-journal-chinese-universities_thesis/0201292348889.html">聚对苯二甲酸乙二酯/聚苯磷酸二苯砜酯体系的性能研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王玉忠&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王玉忠</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑长义&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,郑长义</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴大诚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,吴大诚</a> <span> <a href="/journal-cn-10958/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高等学校化学学报 </a> </span> <span> . 1997</span><span>,第3期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-29985_thesis/020222298381.html">席夫碱型高分子液晶冠醚的合成Ⅰ.聚{4,4'-(α,ω-烷亚甲基二酰氧)苯亚氨基二苯并-18-冠-6}</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张晓静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张晓静</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郭凯&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,郭凯</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张淑媛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张淑媛</a> <span> <a href="/conference-cn-29985/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 两岸三地高分子液晶态与超分子有序态学术研讨会暨第八次全国高分子液晶态与超分子有序态学术论文报告会 </a> <span> <span> . 2002</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314495377.html">对苯二胺/4，4'-二氨基二苯醚/均苯四酸二酐型聚酰亚胺纤维的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄荣辉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 黄荣辉</a> <span> . 2007</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120264437.html">4,6—二羟基—1,3—苯二甲酸和2,3—二羟基—1,4—苯二甲酸的一步合成方法</a> <b>[P]</b> . <span> 中国专利： CN1259303C </span> <span> . 2006.06.14</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120104829249.html">4.6－二羟基－1.3－苯二甲酸和2.3－二羟基－1.4－苯二甲酸的一步合成方法</a> <b>[P]</b> . <span> 中国专利： CN1634849A </span> <span> . 2005-07-06</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130490250812.html">Production of sulphonic acids of benzene, chlorobenzene, naphthalene and mono- and dialkyl benzenes</a> <b>[P]</b> . <span> 外国专利：  GB949852A </span> <span> . 1964-02-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：苯，氯苯，萘，一烷基和二烷基苯磺酸的生产 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130499803583.html">Oligomeric perylene diimide non-fullerene acceptors via direct (hetero)arylation cross-coupling reactions</a> <b>[P]</b> . <span> 外国专利：  US10981936B2 </span> <span> . 2021-04-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：寡聚二酰亚胺非富勒烯受体通过直接（杂）芳基化交叉偶联反应 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130401659230.html">Oligomeric Perylene Diimide Non-Fullerene Acceptors via Direct (Hetero)Arylation Cross-Coupling Reactions</a> <b>[P]</b> . <span> 外国专利：  US2020083457A1 </span> <span> . 2020-03-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过直接（杂）丙烯酸交叉偶联反应的低聚Per二酰亚胺非富勒烯受体 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704019755329','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);">回到顶部</a> </li> <li class="shouye"> <a href="/">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html">关于掌桥</a></li> <li><a href="/help/helpmap.html">资源导航</a></li> <li><a href="/help/helpguide.html">新手指南</a></li> <li><a href="/help/helpcenter.html">常见问题</a></li> <li><a href="/sitemap.html">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704019755329down" data-source="7," data-out-id="gQz1i2mbvN67xwHMoLtY1B5yo0HENrkT/Vy8Yr7l9XIGvek4MfDNAC0x8Akek0wQ," data-f-source-id="7" data-title="Mechanistic study on iron(II)‐mediated direct arylation of benzene with chlorobenzene" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="21753" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Mechanistic study on iron(II)‐mediated direct arylation of benzene with chlorobenzene"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.7"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>