Synthesis, characterization and applications of polyacrylamide grafted fenugreek gum (FG-g-PAM) as flocculant: Microwave vs thermal synthesis approach

摘要

Fenugreek gum is modified using two different techniques: microwave -assisted and thermal synthesis technique of graft copolymerization. The synthesis was done by varying the concentration of acrylamide monomer and CAN initiator to get the best-grafted product. The physicochemical characteristics were determined by elemental analysis, FTIR spectroscopy, SEM, XRD, DSC, TGA, number-average molecular weight and intrinsic viscosity. All the grafted materials were tested by flocculation of different synthetic suspension media as well as river water. The process of deflocculation and refloccculation was also carried out and it was observed that refloccculation process has a good potential as the flocculation efficacy increased to a considerable extent. The flocculation efficacy increased from 92.05% to 9432% upto a maximum of 95.98% in refloccculation process. The flocculation efficacy was found out to be 95.98%, 40.52% and 68.94% respectively kaolin, coal fine and iron ore suspensions. Flocculation was done in kaolin suspension of pH 2, 4, 7 and 10 and at different temperature range of 10 degrees, 25 degrees, 40 degrees and 55 degrees C. It is expected that this material can be used as a highly efficient flocculant in future. (C) 2019 Published by Elsevier B.V.