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(I005)In-situ observation of Al_2O_3 and AlTiO_x inclusions behaviour on the liquid steel surface

机译:(I005)钢液表面Al_2O_3和AlTiO_x夹杂物行为的原位观察

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In the production of IF (interstitial free) steel, Ti will react with oxygen in the molten steel and/or with Al_2O_3during the Ti alloying process. These reactions lead to the formation of Ti containing inclusions, whichinfluence Ti yield during alloying and also steel cleanliness. The formation of non-metallic inclusions such asAl_2O_3, TiO_x, and Al-Ti-O oxides might cause both nozzle clogging during continuous casting and loss of finalproduct quality.1) On the other hand, from the viewpoint of “oxide metallurgy”, Ti containing complex oxidescan be utilized as nuclei for MnS precipitation2), which can serve again as nucleation site for acicular ferriteafter welding or heat treatment, hence improving steel toughness and strength.3,4) It is, therefore, of greatconcern to study the Al_2O_3 and Al-Ti-O inclusion behaviours in the liquid steel.In the present work, in-situ observations using the high temperature confocal scanning laser microscope(CSLM) equipped with an infrared image furnace (IIF) were carried out on industrial samples containingdifferent types of inclusions, i.e. Al_2O_3 and AlTiO_x. After the CSLM tests, assessment of inclusion morphologyand composition was conducted with Environmental Scanning Electron Microscope (E-SEM) on the samplesurface and with Scanning Electron Microscope (SEM) after extraction of the inclusions from the steelsamples. The relevance of the inclusion behaviour with steel composition was elucidated on the basis ofchemical analysis of the samples before and after experiments.
机译:在IF(无间隙)钢的生产中,Ti将在Ti合金化过程中与钢水中的氧气和/或与Al_2O_3反应。这些反应导致形成含钛夹杂物,这会影响合金化期间的钛收率以及钢的清洁度。 Al_2O_3,TiO_x和Al-Ti-O氧化物等非金属夹杂物的形成可能会导致连铸过程中的喷嘴堵塞和最终产品质量的下降。1)另一方面,从“氧化物冶金”的角度来看,Ti可以使用含有复合氧化物的核作为MnS析出的核2),可以在焊接或热处理后再次用作针状铁素体的成核位点,从而提高钢的韧性和强度.3,4)因此,研究Al_2O_3和Al-Ti-O在钢液中的夹杂行为。在目前的工作中,使用装有红外图像炉(IIF)的高温共聚焦扫描激光显微镜(CSLM)对包含不同类型金属的工业样品进行了现场观察。夹杂物,即Al_2O_3和AlTiO_x。经过CSLM测试后,在从钢样中提取夹杂物后,用环境扫描电子显微镜(E-SEM)对样品表面进行了夹杂物形态和成分的评估,并使用扫描电子显微镜(SEM)进行了评估。根据实验前后样品的化学分析,阐明了夹杂物行为与钢成分的相关性。

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