Differences in the g1-ligating properties of 2,4,6-tritertiarybutyl-phosphabenzene, PC5H2But3 and 2,4,6-tritertiarybutyl-1,3,5-triphosphabenzene, P3C3But3

Scott B. Clendenning; Peter B. Hitchcock; Gerard A. Lawless; John F. Nixon; Christopher W. Tate

首页> 外文期刊>Journal of Organometallic Chemistry >Differences in the g1-ligating properties of 2,4,6-tritertiarybutyl-phosphabenzene, PC5H2But3 and 2,4,6-tritertiarybutyl-1,3,5-triphosphabenzene, P3C3But3

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Differences in the g1-ligating properties of 2,4,6-tritertiarybutyl-phosphabenzene, PC5H2But3 and 2,4,6-tritertiarybutyl-1,3,5-triphosphabenzene, P3C3But3

机译：2,4,6-三叔丁基-磷苯，PC5H2But3和2,4,6-三叔丁基-1,3,5-三磷苯，P3C3But3的g1连接特性的差异

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Several g1-complexes of 2,4,6-tritertiarybutylphosphabenzene, PC5H2But 3, have been synthesised and structurally characterised including trans-[PtCl2(PEt3)(g1-PC5But 3)], cis-[PdCl(C10H6CHMe(NMe2)(g1- PC5H2But 3)] and [AuCl(g1-PC5H2But 3)]. NMR spectroscopic evidence is presented for the partial isomerisation in solution of the 2,4,6-tritertiarybutyl-1,3,5-triphosphabenzene complexes trans-[PtCl2(PR3)(g1- P3C3But 3)], (PR3 = PMe3 and PMe2Ph), to the corresponding cis-isomers

机译：合成了2,4,6-三叔丁基磷苯（PC5H2But 3）的几种g1络合物，并对其结构进行了表征，包括反式[PtCl2（PEt3）（g1-PC5But 3）]，顺式[PdCl（C10H6CHMe（NMe2）（g1- PC5H2But 3）]和[AuCl（g1-PC5H2But 3）]。NMR光谱证据表明反式-[PtCl2（PR3）的2,4,6-三叔丁基-1,3,5-三磷苯络合物的溶液中存在部分异构化）（g1- P3C3But 3）]，（PR3 = PMe3和PMe2Ph），形成相应的顺式异构体

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来源
《Journal of Organometallic Chemistry》 |2010年第5期|共4页
作者
Scott B. Clendenning; Peter B. Hitchcock; Gerard A. Lawless; John F. Nixon; Christopher W. Tate;
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正文语种 eng
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Phosphabenzene; Triphosphabenzene; Complexes; Palladium; Platinum; Gold;

机译：磷苯;三磷苯;络合物;钯;铂;金;

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1. Differences in the g1-ligating properties of 2,4,6-tritertiarybutyl-phosphabenzene, PC5H2But3 and 2,4,6-tritertiarybutyl-1,3,5-triphosphabenzene, P3C3But3 [J] . Scott B. Clendenning, Peter B. Hitchcock, Gerard A. Lawless, Journal of Organometallic Chemistry . 2010,第5期

机译：2,4,6-三叔丁基-磷苯，PC5H2But3和2,4,6-三叔丁基-1,3,5-三磷苯，P3C3But3的g1连接特性的差异
2. Prediction of structures and properties of 2,4,6-triamino-1,3,5-triazine-1,3,5-trioxide (MTO) and 2,4,6-trinitro-1,3,5-triazine-1,3,5-trioxide (MTO3N) green energetic materials from DFT and ReaxFF molecular modeling [J] . Naserifar Saber, Zybin Sergey, Ye Cai-Chao, Journal of Materials Chemistry, A. Materials for energy and sustainability . 2016,第4期

机译：2,4,6-三氨基-1,3,5-三嗪-1,3,5-三氧化物（MTO）和2,4,6-三硝基-1,3,5-三嗪-1的结构和性能预测DFT和ReaxFF分子建模得到的3,3-三氧化二（MTO3N）绿色高能材料
3. Synthesis of the 2,4,5-tri-tert-butyl-1,3-diphospholide anion by phosphinidene elimination from 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene on treatment with the amide Li[NPh(SiMe3)] [J] . Clendenning SB, Hitchcock PB, Lappert MF, Chemistry: A European journal . 2007,第25期

机译：酰胺Li处理的2,4,6-三叔丁基1,3,5-三膦苯上的亚膦酸酯消除合成2,4,5-三叔丁基1,3-二磷阴离子。 [NPh（SiMe3）]
4. Intermolecular-interaction and mechanical properties of MNs-plasticizer modified 2,4,6-trinitrotoluene/1,3,5-trinitrohexahydro-1,3,5-triazine mol-ten-energetic-composite(MEC) [C] . Qing Ma, Maoping Wen, Baohui Zheng Annual Conference of the Chinese Society of Micro-Nano Technology . 2015

机译：MNS-增塑剂的分子间相互作用和机械性能改性2,4,6-三硝基甲苯/ 1,3,5-三氨基甲基镁-1,3,5-三嗪摩尔 - 十能 - 复合材料（MEC）
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机译：扫描隧道显微镜（STM）研究四（钴，1,2,5-噻二唑）卟啉（CoTTDPz）和1,3,5-Trithia-2,4,6-三氮杂戊烯基（TTTA）的自由基分子的超分子形成和自旋性质）
6. Cannabinoid Receptor 2 Signalling Bias Elicited by 2,4,6-Trisubstituted 1,3,5-Triazines [O] . Caitlin R. M. Oyagawa, Sara M. de la Harpe, Yurii Saroz, 2018

机译：2,4,6-三取代的1,3,5-三嗪引发的大麻受体2信号偏向
7. Prediction of structures and properties of 2,4,6-triamino-1,3,5-triazine-1,3,5-trioxide (MTO) and 2,4,6-trinitro-1,3,5-triazine-1,3,5-trioxide (MTO3N) green energetic materials from DFT and ReaxFF molecular modeling [O] . Naserifar Saber, Zybin Sergey, Ye Cai-Chao, 2016

机译：2,4,6-三氨基-1,3,5-三嗪-1,3,5-三氧化物（MTO）和2,4,6-三硝基-1,3,5-三嗪-1的结构和性能预测DFT和ReaxFF分子建模得到的3,3-三氧化二（MTO3N）绿色高能材料

Differences in the g1-ligating properties of 2,4,6-tritertiarybutyl-phosphabenzene, PC5H2But3 and 2,4,6-tritertiarybutyl-1,3,5-triphosphabenzene, P3C3But3

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