Kilogram Scale Inverse Vulcanization of Elemental Sulfur to Prepare High Capacity Polymer Electrodes for Li-S Batteries

摘要

The synthesis of high content sulfur copolymers via the inverse vulcanization of elemental sulfur and 1,3-diisopropenylbenzene (DIB) on a one-kilogram scale is reported in a single step process. Investigation into the effects of temperature, reaction scale, and comonomer feed ratios on the inverse vulcanization process of S-8 and DIB were explored to suppress the Trommsdorf effect and enable large scale synthesis of these copolymers. The copolymers were then successfully used as the active cathode materials in Li-S batteries, exhibiting enhanced capacity retention and battery lifetimes (608 mAh/g at 640 cycles) at a C/10 rate. (c) 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 173-177