Analysis of hexavalent chromium in Colla corii asini with on-line sample pretreatment valve-switching ion chromatography

摘要

An ion chromatography (IC) system with on-line sample pretreatment using valve-switching technique was developed for the determination of hexavalent chromium (Cr(VI)) in Colla corii asini. Colla corii asini is a complicated sample with organics as main matrix. In this work, a polymer-based reversed-phase column was used as a pretreatment column. Via valve-switching technique, sample solution with target ions were eluted from a collection loop to analytical columns, with matrix eliminated on-line. Under the optimized separation conditions, the method showed good linearity (r= 0.9998) in the range of 0.004-1.0. mg/L and satisfactory repeatability (RSD < 3%, n= 6). The limit of detection (LOD) was 1.4 μg/L (S/N = 3). The average spiked recoveries of Cr(VI) were 93.4-102.0%. The result showed that the on-line sample pretreatment IC system was convenient and practical for the determination of trace Cr(VI) in Colla corii asini samples.