Complex permittivity of FeCl_3/AOT/CCl_4 microemulsions probed by AC impedance spectroscopy

摘要

The complex permittivity of FeCl_3/AOT/CCl_4 microemulsions in the 1-10~5 Hz frequency range has been measured by the conventional AC complex impedance technique. Measurements as a function of the volume fraction of the dispersed phase (FeCl_3 + AOT) and temperature at fixed salt-to-AOT molar ratio (R, R = 0.5) show that the entrapment of FeCl_3 clusters significantly enhances the local permittivity of the AOT reverse micelles and the number density of charge carriers resulting from the peculiar state of the confined inorganic salt. An estimate of the apparent static permittivity of the FeCl_3 ionic clusters entrapped in the core of AOT reverse micelles gives the very high and quite surprisingly value of about 237. Moreover, a thorough analysis of conductivity data and of their temperature dependence strongly supports the hypothesis that the charge transport in these systems is mainly sustained by a mechanism of hopping consisting in the continuous jumping of charged species within supra-micellar aggregates of AOT reverse micelles whose aggregation is driven by fluctuating opposite charges on contacting micelles.