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Investigation of corrosion behaviour of hydrogenated 7075-T6 aluminum alloy

机译:氢化7075-T6铝合金腐蚀行为的研究。

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摘要

The corrosion behaviour of high strength aluminium alloy type 7075-T6 precharged with hydrogen for various charging times was investigated using electrochemical polarization and free corrosion potentials measurement techniques. The results showed that the precharged 7075-T6 aluminium alloy with hydrogen exhibited lower open-circuit (OCP) and breakdown potentials in deaerated 0.5 M NaCl than those for the non-hydrogenated material. Moreover, the OCP and breakdown potentials decreased with increasing the precharging time. Microscopic observations of the exposed surfaces revealed that intergranular attack was formed in non-hydrogenated specimens whereas mixed mode of attack (i.e. intergran-ular and transgranular) were formed in the precharged ones during potentiostatic polarization. Moreover, the pits formed during the free corrosion potential testing were observed to be larger on the exposed surfaces of hydrogen precharged specimens. The severity of attack and pitting was observed to increase with increasing the precharging time. Consequently, the corrosion resistance of hydrogen precharged of 7075-T6 aluminium alloy with hydrogen was lower than that for non-hydrogenated material.
机译:使用电化学极化和自由腐蚀电位测量技术研究了预充氢气的高强度7075-T6型铝合金在各种充电时间下的腐蚀行为。结果表明,预充氢的7075-T6铝合金在脱气的0.5 M NaCl中比未氢化的材料具有更低的开路(OCP)和击穿电位。此外,OCP和击穿电位随着预充电时间的增加而降低。裸露表面的显微镜观察表明,在未加氢的样品中形成了晶间侵蚀,而在恒电位极化过程中,在预充电的试样中形成了混合的侵蚀模式(即晶间和跨晶)。此外,观察到在自由腐蚀电位测试期间形成的凹坑在预充氢试样的暴露表面上更大。随着预充电时间的增加,侵蚀和点蚀的严重性增加。因此,用氢预填充了7075-T6铝合金的氢的耐蚀性低于未氢化的材料。

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