Effect of zinc oxide on the viscosity, tack, and peel strength of ENR 25-based pressure-sensitive adhesives

摘要

Viscosity, loop tack, and peel strength of epoxiclized natural rubber (ENR 25 grade)-based pressure-sensitive adhesive was studied in the presence of zinc oxide. The zinc oxide concentration was varied from 10-50 parts per hundred parts of rubber (phr). Coumarone-indene resin with loading from 20 to 100 phr was chosen as the tackifier resin. Toluene was used as the solvent throughout the experiment. The adhesive was coated on the substrate using a SHEEN hand coater to give a coatin-thickness of 60 pm. Viscosity of the adhesive was determined by a HAAKE Rotary Viscometer whereas the loop tack and peel strength were measured by a Llyod Adhesion Tester operating at 30 cm/min. Results show that viscosity and loop tack of adhesive increases with increasing zinc oxide concentration. For the peel strength, it increases with zinc oxide concentration up to 30-40 phr and drops after the maximum value. This observation is associated with the effect of varying degree of wettability of the adhesive on the substrate. However, for a fixed zinc oxide concentration, loop tack and peel strength exhibit maximum value at 80 phr resin loading after which both properties decrease with further addition of resin, an observation which is attributed to phase inversion. From this study, the optimum adhesion property is achieved by using 40 phr zinc oxide and 80 phr coumarone-indene resin. (c) 2007 Wiley Periodicals, Inc.