Study on emulsion and suspension in situ polymerization

摘要

A novel and simple method of emulsion and suspension in situ polymerization was designed for preparing a composite of polystyrene containing core-shell emulsion particles. The advantage of this method was that it did not need a complex process, such as emulsion breaking, washing, drying, and so on, during transforming from emulsion polymerization to suspension polymerization. First, the core-shell particles of poly(styrene/bisphenol A dimethyl methacrylate)/polystyrene [P(St/BPADA)/PS] with crosslinking structure were synthesized by emulsion polymerization. Then the latex was broken with electrolyte dripping and the emulsion particles became swollen and transformed into the monomer in the suspension polymerization system. Thus the emulsion and suspension in situ polymerization could be carried out successfully. The mechanism of the process was investigated in detail. (C) 2004 Wiley Periodicals, Inc.