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Investigation of Radiation-Induced Free Radicals and Luminescence Properties in Fresh Pomegranate Fruits

机译:石榴果实中辐射诱发的自由基及其发光特性的研究

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摘要

Radiation-induced free radicals and luminescence properties were investigated in γ-irradiated (0—3 kGy) pomegranate (Punica granatum L.) fruits. Photostimulated luminescence (PSL) analysis showed limited applicability, and only 3 kGy-irradiated pomegranates showed positive PSL values (>5000 PCs). Thermoluminescence (TL) glow curve features, such as intensity and the presence of maximum glow peak in radiation-specific temperature range (150—250 °C), provided definite proof of irradiation, and the TL ratios (TL1/TL2) also confirmed the reliability of TL results. Scanning electron microscopy energy dispersive X-ray (SEM-EDX) analysis of the separated minerals showed that feldspar and quartz minerals were responsible for the luminescence properties. Radiation-induced cellulose radicals were detected in the seeds and rinds by ESR analysis. The ESR results were better in freeze-dried samples than in alcohol-extracted ones. A positive correlation was found between the ESR and TL signal intensities and irradiation doses; however, the most promising detection of the irradiation status was possible through TL analysis.
机译:研究了γ-辐照(0-3 kGy)石榴(石榴)果实的辐射诱导自由基和发光特性。光刺激发光(PSL)分析显示适用性有限,只有3 kGy辐照的石榴显示正PSL值(> 5000 PCs)。热致发光(TL)辉光曲线特征,例如强度和在辐射特定温度范围(150-250°C)中最大辉光峰的存在,提供了确定的辐照证据,并且TL比(TL1 / TL2)也证实了TL结果的可靠性。扫描电子显微镜能量色散X射线(SEM-EDX)分析分离出的矿物表明,长石和石英矿物是造成发光特性的原因。通过ESR分析在种子和果皮中检测到辐射诱导的纤维素自由基。冷冻干燥样品的ESR结果优于酒精提取样品。在ESR和TL信号强度与照射剂量之间发现正相关。但是,通过TL分析,最有前途的辐照状态检测是可能的。

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