Isolation and Structural Characterization of Anthocyanin-furfuryl Pigments

摘要

Condensation reactions of malvidin-3-glucoside with two representative oak wood furanic aldehydes (furfural and methylfurfural) were conducted in wine-like model solutions. Methylfurfural led to the formation of malvidin-3-glucoside-methylfurfural (603 mlz), whereas furfural led to the formation of malvidin-3-glucoside-furfural (589 mlz). The latter was structurally characterized by 1D and 2D NMR, allowing an elucidation of the formation mechanism of these anthocyanin-furanic aldehyde adducts in the absence of flavanols.