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APS TBC performance on directionally-solidified superalloy substrates with HVOF NiCoCrAlYHfSi bond coatings

机译:具有HVOF NiCoCrAlYHfSi粘结涂层的定向凝固高温合金基底上的APS TBC性能

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摘要

Directionally-solidified (DS) superalloy components with advanced thermal barrier coatings (TBC) to lower the metal operating temperature have the potential to replace more expensive single crystal superalloys for large land-based turbines. In order to assess relative TBC performance, furnace cyclic testing was used with superalloys 1483, X4 and Hf-rich DS 247 substrates and high velocity oxygen fuel (HVOF)-NiCoCrAlYHfSi bond coatings at 1100 degrees C with 1-h cycles in air with 10% H2O. With these coating and test conditions, there was no statistically-significant effect of substrate alloy on the average lifetime of the air plasma sprayed (APS) yttria-stabilized zirconia (YSZ) top coatings on small coupons. Using photo-stimulated luminescence piezospectroscopy maps at regular cycling intervals, the residual compressive stress in the alpha-Al2O3 scale underneath the YSZ top coating and on a bare bond coating was similar for all three substrates and delaminations occurred at roughly the same rate and frequency. X-ray fluorescence (XRF) measurements collected from the bare bond coating surface revealed higher Ti interdiffusion occurring with the 1483 substrate, which contained the highest Ti content. (C) 2015 Elsevier B.V. All rights reserved.
机译:具有先进的热障涂层(TBC)的定向凝固(DS)超级合金组件可降低金属运行温度,有可能取代用于大型陆基涡轮机的更昂贵的单晶超级合金。为了评估相对的TBC性能,在1100°C的空气中以1h循环在1100摄氏度下对超级合金1483,X4和富H的DS 247基材以及高速氧燃料(HVOF)-NiCoCrAlYHfSi粘结涂层进行了炉循环试验%H2O。在这些涂层和测试条件下,基体合金对小试件上的空气等离子喷涂(APS)氧化钇稳定的氧化锆(YSZ)顶层涂层的平均寿命没有统计学意义的影响。使用光激发的发光压电光谱图以规则的循环间隔,YSZ顶涂层下面和裸键涂层上的alpha-Al2O3尺度上的残余压应力对于所有三种基材都是相似的,并且分层发生的速率和频率大致相同。从裸结合涂层表面收集的X射线荧光(XRF)测量结果显示,1483基材发生了更高的Ti相互扩散,其中Ti含量最高。 (C)2015 Elsevier B.V.保留所有权利。

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