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Selective pulsed laser stripping of TiAlN erosion-resistant coatings: Effect of wavelength and pulse duration

机译:TiAlN耐腐蚀涂层的选择性脉冲激光剥离:波长和脉冲持续时间的影响

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摘要

The lifetime of titanium-alloy aerospace parts can be greatly enhanced by the application of erosion-resistant coatings (ERC). After many hours in service, the coating will inevitably begin to deteriorate. To permit re-coating and repair of the parts, the coating should be removed. We present here a first attempt to strip TiN-based, 20. μm-thick, coatings while comparing the suitability of two pulsed lasers: a femtosecond Ti:Sapphire laser emitting at 800. nm, and a nanosecond excimer laser centered at 248. nm. Following initial comparison of ablation thresholds for each laser, we optimized four critical laser parameters: power, beam diameter, stage speed and step distance. The results indicate that surface roughness can be improved by 35% with the femtosecond laser in comparison with the nanosecond laser, while the higher energy per pulse offered by the latter one accelerates the etch rate by one order of magnitude. Surface composition analysis confirmed full removal of the coating and higher oxidization of the substrate with the excimer laser. Nanoindentation measurements on the polished cross-section of stripped samples show that the ablation process does not influence the hardness of the remaining substrate. To increase selectivity, plume emission spectroscopy has been investigated, in order to control, in real time, the material removal in regions where the coating thickness may vary.
机译:钛合金航空零件的使用寿命可以通过应用抗腐蚀涂层(ERC)大大提高。在使用多个小时后,涂层将不可避免地开始变质。为了允许重新喷涂和维修零件,应去除涂层。我们在此首次尝试剥离基于TiN的厚度为20μm的涂层,同时比较两种脉冲激光器的适用性:飞秒发射的800纳米飞秒Ti:蓝宝石激光器和中心对准248. nm的纳秒准分子激光器。 。在初步比较每种激光的烧蚀阈值之后,我们优化了四个激光关键参数:功率,光束直径,载物台速度和步距。结果表明,与纳秒激光器相比,飞秒激光器的表面粗糙度可提高35%,而后者提供的每脉冲更高的能量将蚀刻速率提高了一个数量级。表面成分分析证实了用准分子激光完全清除了涂层并提高了基材的氧化程度。在剥离样品的抛光横截面上进行的纳米压痕测量表明,烧蚀过程不会影响剩余基材的硬度。为了增加选择性,已经研究了羽流发射光谱法,以便实时控制涂层厚度可能变化的区域中的材料去除。

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