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首页> 外文期刊>The Journal of Chemical Physics >Free volume distribution of nearly jammed hard sphere packings
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Free volume distribution of nearly jammed hard sphere packings

机译:几乎卡住的硬球填料的自由体积分布

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摘要

We calculate the free volume distributions of nearly jammed packings of monodisperse and bidisperse hard sphere configurations. These distributions differ qualitatively from those of the fluid, displaying a power law tail at large free volumes, which constitutes a distinct signature of nearly jammed configurations, persisting for moderate degrees of decompression. We reproduce and explain the observed distribution by considering the pair correlation function within the first coordination shell for jammed hard sphere configurations. We analyze features of the equation of state near jamming, and discuss the significance of observed asphericities of the free volumes to the equation of state.
机译:我们计算了单分散和双分散硬球构型几乎堵塞的填料的自由体积分布。这些分布在质量上与流体的分布不同,在大的自由体积处显示出幂律尾部,这构成了几乎卡死的配置的明显特征,并持续了中等程度的减压。我们通过考虑第一个配位壳内的成对相关函数来模拟和解释观察到的分布,以解决阻塞的硬球配置。我们分析了接近干扰状态方程的特征,并讨论了观察到的自由体积非球面度对状态方程的意义。

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