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Argon nucleation in a cryogenic supersonic nozzle

机译:低温超声喷嘴中的氩成核

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We have measured pressures p and temperatures T corresponding to the maximum nucleation rateof argon in a cryogenic supersonic nozzle apparatus where the estimated nucleation rates are J=10~(17±1)cm~(-3)s~(-1). AsTincreases from 34 to 53 K,pincreases 0.47 8 kPa. Under theseconditions, classical nucleation theory predicts nucleation rates of 11-13 orders of magnitude lowerthan the observed rates while mean field kinetic nucleation theory predicts the observed rates within1 order of magnitude. The current data set appears consistent with the measurements of Hand et al.[J. Chem. Phys. 127, 154506 (2007)] in the cryogenic nucleation pulse chamber. Combining the twodata sets suggests that classical nucleation theory fails because it overestimates both the criticalcluster size and the excess internal energy of the critical clusters.
机译:我们在低温超音速喷嘴装置中测量了对应于氩气最大成核率的压力p和温度T,其中估计成核率为J = 10〜(17±1)cm〜(-3)s〜(-1)。 As从34 K增加到53 K,增加0.47 8 kPa。在这些条件下,经典成核理论预测成核速率比观测到的速率低11-13个数量级,而平均场动力学成核理论预测成核速率在1个数量级内。当前数据集似乎与Hand等人的测量结果一致。化学物理127,154506(2007)]在低温成核脉冲室中。结合这两个数据集表明,经典成核理论失败了,因为它高估了临界团簇的大小和临界团簇的多余内部能量。

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