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Fluctuating dynamics of nematic liquid crystals using the stochastic method of lines

机译:使用线的随机方法向列液晶的波动动力学

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We construct Langevin equations describing the fluctuations of the tensor order parameter Qαβ in nematic liquid crystals by adding noise terms to time-dependent variational equations that follow from the Ginzburg-Landau-de Gennes free energy. The noise is required to preserve the symmetry and tracelessness of the tensor order parameter and must satisfy a fluctuation-dissipation relation at thermal equilibrium. We construct a noise with these properties in a basis of symmetric traceless matrices and show that the Langevin equations can be solved numerically in this basis using a stochastic version of the method of lines. The numerical method is validated by comparing equilibrium probability distributions, structure factors, and dynamic correlations obtained from these numerical solutions with analytic predictions. We demonstrate excellent agreement between numerics and theory. This methodology can be applied to the study of phenomena where fluctuations in both the magnitude and direction of nematic order are important, as for instance, in the nematic swarms which produce enhanced opalescence near the isotropic-nematic transition or the problem of nucleation of the nematic from the isotropic phase.
机译:通过将噪声项添加到随时间变化的从Ginzburg-Landau-de Gennes自由能得到的变分方程中,我们构造了描述向列液晶中张量阶数参数Qαβ波动的Langevin方程。需要噪声来保持张量阶数参数的对称性和无痕性,并且必须在热平衡时满足波动-耗散关系。我们在对称无迹矩阵的基础上构造了具有这些属性的噪声,并表明可以在此基础上使用随机方法的线法对Langevin方程进行数值求解。通过比较从这些数值解获得的平衡概率分布,结构因子和动态相关性与解析预测来验证数值方法的有效性。我们证明了数值与理论之间的卓越一致性。该方法学可用于研究向列顺序的大小和方向均很重要的现象,例如向列群在各向同性向列相变附近产生增强的乳光或向列相成核问题各向同性相

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