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首页> 外文期刊>The Journal of Chemical Physics >Closed-form expressions of the chemical potential for integral equation closures with certain bridge functions
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Closed-form expressions of the chemical potential for integral equation closures with certain bridge functions

机译:具有某些桥函数的积分方程闭合的化学势的闭合式表达式

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摘要

A general, path-independent expression is derived for the excess chemical potential of integral equation closure approximations that contain a bridge function which depends on a renormalized indirect correlation function. Closed-form results are obtained for various cases, among them a partial series expansion of the hypernetted chain closure.
机译:对于积分方程闭合逼近的过剩化学势,可以得出一个一般的,与路径无关的表达式,其中包含一个桥函数,该桥函数取决于重新归一化的间接相关函数。在各种情况下都可获得闭合形式的结果,其中包括超网状链闭合的部分级数展开。

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