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首页> 外文期刊>The Journal of Chemical Physics >Relativistic and nonrelativistic solutions for diatomic molecules in the presence of double ring-shaped Kratzer potential
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Relativistic and nonrelativistic solutions for diatomic molecules in the presence of double ring-shaped Kratzer potential

机译:双环状Kraztz势存在下双原子分子的相对论和非相对论解

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The authors investigate solutions of the three dimensional Klein-Gordon and Schrodinger equations in the presence of a new exactly solvable potential of V(r,theta)=-2D_e(r_e/r-(1/2)(r_e~2/r2))+b/r2 sin2 theta+a/r2 cos2 8 type,the so-called double ring-shaped Kratzer potential.For a diatomic molecule system in double ring-shaped Kratzer potential,the exact bound state energy eigenvalues and corresponding wave functions have been determined within the framework of the asymptotic iteration method.Bound state eigenfunction solutions used in applications related to molecular spectroscopy are obtained in terms of confluent hypergeometric function and Jacobi polynomial.This new formulation is tested by calculating the energies of rovibrational states of a number of diatomic molecules.Also,the author-prove that in the nonrelativistic limit c->infinity,where c is the speed of light,solutions of the Klein-Gordon system converge to those of the Schrodinger system.
机译:作者研究了存在新的V(r,theta)=-2D_e(r_e / r-(1/2)(r_e〜2 / r2)的完全可解势的情况下三维Klein-Gordon和Schrodinger方程的解)+ b / r2 sin2 theta + a / r2 cos2 8型,即所谓的双环状Kratzer势。对于双环状Kratzer势的双原子分子系统,确切的束缚态能量本征值和相应的波动函数具有在渐近迭代法的框架内确定。根据合流超几何函数和Jacobi多项式,获得了与分子光谱相关的应用中的束缚态本征函数解,并通过计算许多函数的振动态能量来测试该新公式。此外,作者证明了在非相对论极限c->无穷大(其中c是光速)的情况下,Klein-Gordon系统的解收敛于Schrodinger系统的解。

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