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首页> 外文期刊>The Journal of Chemical Physics >Coherent exciton transport in dendrimers and continuous-time quantum walks
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Coherent exciton transport in dendrimers and continuous-time quantum walks

机译:树枝状聚合物和连续时间量子行走中的相干激子传输

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摘要

We model coherent exciton transport in dendrimers by continuous-time quantum walks.For dendrimers up to the second generation the coherent transport shows perfect recurrences when the initial excitation starts at the central node.For larger dendrimers,the recurrence ceases to be perfect,a fact which resembles results for discrete quantum carpets.Moreover,depending on the initial excitation site,we find that the coherent transport to certain nodes of the dendrimer has a very low probability.When the initial excitation starts from the central node,the problem can be mapped onto a line which simplifies the computational effort.Furthermore,the long time average of the quantum mechanical transition probabilities between pairs of nodes shows characteristic patterns and allows us to classify the nodes into clusters with identical limiting probabilities.For the(space)average of the quantum mechanical probability to be still or to be again at the initial site,we obtain,based on the Cauchy-Schwarz inequality,a simple lower bound which depends only on the eigenvalue spectrum of the Hamiltonian.
机译:我们通过连续时间量子游走对树枝状聚合物中的相干激子输运进行建模。对于直到第二代的树枝状聚合物,当初始激发从中心节点开始时,相干输运显示出完美的递归。对于较大的树枝状聚合物,递归不再是完美的,这是事实这类似于离散量子地毯的结果。此外,根据初始激发位点,我们发现相干传输到树枝状聚合物某些节点的可能性非常低。当初始激发从中心节点开始时,可​​以映射问题此外,节点对之间的量子力学跃迁概率的长时间平均表现出特征模式,并允许我们将节点分类为具有相同极限概率的簇。根据柯西·舒瓦(Cauchy-Schwa),我们获得了在初始位置处静止或再次出现的量子力学概率rz不等式,一个简单的下界,仅取决于哈密顿量的特征值谱。

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