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Effects of pulsed low frequency electromagnetic fields on water using photoluminescence spectroscopy:Role of bubble/water interface

机译:脉冲低频电磁场对光致发光光谱的影响:气泡/水界面的作用

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摘要

The effects of a pulsed low frequency electromagnetic field were investigated on photoluminescence of well characterized water and prepared under controlled conditions (container,atmospheric,electromagnetic,and acoustic environments).When reference water samples were excited at 260 nm,two wide emission bands centered at 345 nm (3.6 eV) and 425 nm (2.9 eV) were observed.By contrast under 310 nm excitation,only one band appeared at 425 nm.Interestingly,electromagnetic treatment (EMT) induced,at both excitation wavelengths,a decrease (around 70%) in the 425 nm band relative photoluminescence intensity.However,no difference between reference and treated sample was observed in the 345 nm band.Other experiments,performed on outgassed samples (reference and treated),show that the emission bands (position,shape,intensity) under excitation at 260 nm and 310 nm were similar and close to the corresponding bands of the treated nonoutgassed samples.Similar effects were observed on photoluminescence excitation of water samples.Two excitation bands monitored at 425 nm were observed at 272 nm and 330 nm.After EMT and/or outgassing,a decrease (>60%) was observed in the intensity of these two bands.Altogether,these results indicate that electromagnetic treatment and/or outgassing decrease in a similar fashion the photoluminescence intensity in water samples.They also suggest that this effect is most likely indirectly attributed to the presence of gas bubbles in water.The possible role of hydrated ionic shell around the bubbles in the observed extraluminescence is discussed.
机译:研究了脉冲低频电磁场对特性良好的水的光致发光的影响,并在受控条件下(容器,大气,电磁和声环境)制备了该水。当参考水样品在260 nm处激发时,两个宽发射带集中在观察到345 nm(3.6 eV)和425 nm(2.9 eV)。通过在310 nm激发下的对比,在425 nm处仅出现一个谱带。有趣的是,在两个激发波长下均进行了电磁处理(EMT),减少了(大约70 %)在425 nm波段的相对光致发光强度。但是,在345 nm波段中未观察到参比样品与处理后样品之间的差异。在脱气样品(参比样品和已处理样品)上进行的其他实验显示发射谱带(位置,形状(强度)在260 nm和310 nm激发下相似并且接近处理后的未脱气样品的相应谱带。在光致发光上观察到相似的影响水样品的激发。在272 nm和330 nm处观察到两个在425 nm处监测到的激发带.EMT和/或除气后,这两个谱带的强度降低了(> 60%)。总的来说,这些结果表明电磁处理和/或除气以类似的方式减少了水样中的光致发光强度。他们还表明,这种影响很可能间接地归因于水中气泡的存在。讨论了观察到的发光。

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