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首页> 外文期刊>The Journal of Chemical Physics >Shear stress relaxation in liquids
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Shear stress relaxation in liquids

机译:液体中的剪切应力松弛

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摘要

We show that at high densities,as the system size decreases,liquid becomes able to permanently sustain increasing internal shear stress after a constant deformation,although the other characteristic liquid properties,such as the pair distribution function and diffusion coefficient do not change under strain.The system size necessary for observation of this effect increases with the decrease in temperature,and it is stronger in pair potentials with steeper repulsive part.We relate this result to the size of the "cooperatively rearranging regions" of the Adam-Gibbs theory of glass transition.
机译:我们表明,在高密度下,随着系统尺寸的减小,液体在恒定的变形后变得能够永久地承受不断增加的内部剪切应力,尽管在应变下其他液体特性(如对分布函数和扩散系数)不会改变。观察该效应所需的系统尺寸随温度的降低而增加,并且对势更强且排斥部分更陡。我们将此结果与Adam-Gibbs玻璃理论的“合作重排区域”的大小相关联过渡。

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