Monte Carlo simulation of dendrimers in variable solvent quality

摘要

We study via lattice Monte Carlo simulation and Flory theory the properties of g=1-6 dendrimers in variable solvent quality.For all the generations studied,we find that the radius of gyration R_g collapses significantly (factor of 2) going from athermal to extreme poor solvent conditions,indicating that varying solvent quality is an effective means of controlling dendrimer size.We also find that in athermal,thetha,and extreme poor solvent conditions,the radius of gyration of dendrimers scales with the total number of monomers roughly as R_g approx N~(1/3).However,a more careful analysis shows that in athermal and thetha solvents,there is,in fact,a small but systematic deviation of R_g from R_g~N~(1/3) scaling and the simulation data is described better by the Flory theory prediction of R_g approx N~(1/5)[(g+1)m]~(2/5) in athermal solvents and _g approx Nl~(1/4)[(g+ 1 )m]~(1/4) in theta solvents.We also find for our simulation data that stronger deviations from constant density scaling are possible,with scaling behavior as shallow as R_g approxy N~(0.26) possible for solvent conditions in between 6 and the completely collapsed state.It is evident therefore that dendrimers do not obey (or even approximately obey) R_g approx N~(1/3) scaling under all solvent conditions.Under all solvent conditions,we find that the intramolecular density is dense corelike (i.e.,the density maximum is in the interior of the dendrimer) and terminal groups are delocalized throughout the dendrimer.