Catalytic oxidation of hydrogen on free platinum clusters

摘要

The adsorption of hydrogen (deuterium) and oxygen on neutral platinum clusters has been investigated in a cluster beam experiment. The beam passes through two low-pressure reaction cells and the clusters, with and without adsorbed molecules, and detected by laser ionization and mass spectrometry. Both H_2 and O_2 adsorb efficiently on the platinum clusters with only moderate variations with cluster size in the investigated range, i.e., between 7 and 30 atoms. The coadsorption of H_2 and O_2 results in the formation and desorption of H_2O, detected as a decreasing number of adsorbed oxygen atoms with an increasing number of collisions with H_2 molecules. The water-formation reaction proceeds efficiently on all investigated clusters with more than seven atoms.