An entry to 1,6-dioxaspiro[4.6]undecanes and 1,7-dioxaspiro[5.6]dodecanes

Anthony Ollivier; Marie-Eve Sinibaldi; Loic Toupet

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >An entry to 1,6-dioxaspiro[4.6]undecanes and 1,7-dioxaspiro[5.6]dodecanes

【24h】

An entry to 1,6-dioxaspiro[4.6]undecanes and 1,7-dioxaspiro[5.6]dodecanes

机译：1,6-二氧杂螺[4.6]十一烷和1,7-二氧杂螺[5.6]十二烷的条目

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Ketones 11a-c obtained by iterative alkylation of acetone N,N-dimethylhydrazone with iodides 6 and 8a,b or epoxide 9 followed by SiO2/H2O-induced cleavage of the hydrazone were quantitatively transformed into l,6-dioxaspiro[4.6]imdecanes 12a,c and 1,7-dioxaspiro[5.6]dodecanes 12b using Yb(OTf)3 in CH3CN.

机译：通过将丙酮N，N-二甲基hydr与碘化物6和8a，b或环氧化物9迭代烷基化，然后SiO2 / H2O诱导的the裂解，将得到的酮11a-c定量转化为1,6-二氧杂螺并[4.6]十二烷12a ，c和在CH 3 CN中使用Yb（OTf）3的1,7-二氧杂螺[5.6]十二烷12b。

著录项

来源
《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2010年第31期|共3页
作者
Anthony Ollivier; Marie-Eve Sinibaldi; Loic Toupet;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
Spiroketal; Cyclization; Hydrazone; Alkylation;

机译：螺环;环化;H;烷基化;

相似文献

外文文献
中文文献
专利

1. An entry to 1,6-dioxaspiro[4.6]undecanes and 1,7-dioxaspiro[5.6]dodecanes [J] . Anthony Ollivier, Marie-Eve Sinibaldi, Loic Toupet Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2010,第31期

机译：1,6-二氧杂螺[4.6]十一烷和1,7-二氧杂螺[5.6]十二烷的条目
2. Crystal structures of (3S*,4S*,5S*,6S*)-3,4-epoxy-1,7-dioxaspiro[5.5]undecan-5-ol, (3R*,5S*,6S*)-1,7-dioxaspiro[5.5]undecane-3,5-diyl diacetate and(4S*,5S*6S*)-1,7-dioxaspiro[5.5]undecane-4,5-diol [J] . Brimble MA, Johnston A, Hambley TW, Australian Journal of Chemistry: A Journal for the Publication of Original Research in All Branches of Chemistry . 1997,第2期

机译：（3S *，4S *，5S *，6S *）-3,4-环氧-1,7-二氧杂螺[5.5]十一烷-5-醇，（3R *，5S *，6S *）-1的晶体结构， 7-二氧杂螺[5.5]十一烷-3,5-二乙酸二乙酸酯和（4S *，5S * 6S *）-1,7-二氧杂螺[5.5]十一烷-4,5-二醇
3. Flexible synthesis of enantiomerically pure 2,8-dialkyl-1,7-dioxaspiro[5.5]undecanes and 2,7-dialkyl-1,6-dioxaspiro[4.5]decanes from propargylic and homopropargylic alcohols [J] . Schwartz BD, Hayes PY, Kitching W, The Journal of Organic Chemistry . 2005,第8期

机译：从炔丙醇和高炔丙醇灵活合成对映体纯的2,8-二烷基-1,7-二氧杂螺[5.5]十一烷和2,7-二烷基-1,6-二氧杂螺[4.5]癸烷
4. SYNTHESIS OF THE OPTICALLY ACTIVE FORMS OF 4,10-DIHYDROXY-1,7-DIOXASPIRO 5,5 UNDECANE AND THEIR CONVERSION TO THE ENANTIOMERS OF 1,7-DIOXASPIRO5.5UNDECANE, THE OLIVE FLY PHEROMONE [C] . T. Uematsu, K.Mori International Congress of Pesticide Chemistry . 1986

机译：合成4,10-二羟基-1,7-Dioxaspiro 5,5的非甲烷的光学活性形式及其转化为1,7-二氧化硅的对映体5.5未甲烷，橄榄蝇信息素
5. 3-(4-Bromobenzylidene)-15-dioxaspiro5.5undecane-24-dione [O] . Wu-Lan Zeng 2011

机译：3-（4-溴亚苄基）-15-二氧杂螺5.5十一烷-24-二酮
6. Synthesis of Dacus Pheromone, 1,7-Dioxaspiro5.5Undecane and Its Encapsulation in PLLA Microspheres for Their Potential Use as Controlled Release Devices [O] . Stavroula A. Zisopoulou, Christina K. Chatzinikolaou, John K. Gallos, 2020

机译：Dacus Pheroomone的合成，1,7-二恶英5.5未甲烷及其在PLLA微球中的封装，其潜在用途作为控释装置
7. Convenient Synthesis of 1,7-Dibromo- and 1,7-Dichloro-Pentacyclo(5.4.0.0 2,6.0 3,10 .0 5,9) Undecane-8, 11-Diones. [R] . Marchand, A. P., Annapurna, P. 1989

机译：方便合成1,7-二溴 - 和1,7-二氯 - 五环（5.4.0.0 2,6.0 3,10 .0 5,9）十一烷-8,11-二酮。

An entry to 1,6-dioxaspiro[4.6]undecanes and 1,7-dioxaspiro[5.6]dodecanes

摘要

著录项

相似文献

相关主题

期刊订阅