Sequential Baylis-Hillman/RCM protocol for the stereoselective synthesis of (+)-MK7607 and (+)-streptol

Palakodety Radha Krishna; Raghu Ram Kadiyala

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Sequential Baylis-Hillman/RCM protocol for the stereoselective synthesis of (+)-MK7607 and (+)-streptol

机译：顺序Baylis-Hillman / RCM协议，用于（+）-MK7607和（+）-链烯醇的立体选择性合成

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摘要

Sequential Baylis-Hillman/ring-closing metathesis (RCM) approach toward the total synthesis of (+)-MK7607 and (+)-streptol starting from (R,R)-tartaric acid is reported.

机译：报道了从（R，R）-酒石酸开始对（+）-MK7607和（+）-链烷醇进行全合成的顺序Baylis-Hillman /闭环复分解（RCM）方法。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2010年第19期|共3页
作者
Palakodety Radha Krishna; Raghu Ram Kadiyala;
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正文语种 eng
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Cyclitols; Diastereoselective Baylis-Hillman reaction; Ring-closing metathesis; Hoveyda-Grubbs catalyst; Sharpless asymmetric epoxidation; (R; R)-Tartaric acid;

机译：环醇;非对映选择性Baylis-Hillman反应;闭环易位;Hoveyda-Grubbs催化剂;无尖锐的不对称环氧化;（R;R）-酒石酸;

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Sequential Baylis-Hillman/RCM protocol for the stereoselective synthesis of (+)-MK7607 and (+)-streptol

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