Highly diastereoselective synthesis of tetrahydrobenzofuranones by palladium-catalyzed reaction of propargylic carbonates with 2-substituted cyclohexane-1,3-diones

Masahiro Yoshida; Mariko Higuchi; Kozo Shishido

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >Highly diastereoselective synthesis of tetrahydrobenzofuranones by palladium-catalyzed reaction of propargylic carbonates with 2-substituted cyclohexane-1,3-diones

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Highly diastereoselective synthesis of tetrahydrobenzofuranones by palladium-catalyzed reaction of propargylic carbonates with 2-substituted cyclohexane-1,3-diones

机译：钯催化的碳酸炔丙基酯与2-取代的环己烷-1,3-二酮的钯催化高度非对映选择性合成四氢苯并呋喃酮

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The reaction of propargylic carbonates with 2-substituted cyclohexane-1,3-diones in the presence of palladium catalyst is described.Substituted tetrahydrobenzofuranones having a quaternary carbon stereocenter were synthesized in a highly diastereoselective manner.

机译：描述了炔丙基碳酸酯与2-取代的环己烷-1,3-二酮在钯催化剂存在下的反应。以高度非对映选择性的方式合成了具有季碳立构中心的四氢苯并呋喃呋喃酮。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2008年第10期|共4页
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Masahiro Yoshida; Mariko Higuchi; Kozo Shishido;
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1. Highly diastereoselective synthesis of tetrahydrobenzofuranones by palladium-catalyzed reaction of propargylic carbonates with 2-substituted cyclohexane-1,3-diones [J] . Masahiro Yoshida, Mariko Higuchi, Kozo Shishido Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2008,第10期

机译：钯催化的碳酸炔丙基酯与2-取代的环己烷-1,3-二酮的钯催化高度非对映选择性合成四氢苯并呋喃酮
2. Highly regioselective synthesis of 2,3-disubstituted indenes via a novel palladium-catalyzed cyclization reaction of propargylic carbonates with carbon nucleophiles [J] . Duan XH, Guo LN, Bi HP, Organic letters . 2006,第25期

机译：通过丙炔碳酸酯与碳亲核试剂的新型钯催化环化反应，高区域选择性合成2,3-二取代的茚
3. Highly regioselective synthesis of 2,3-disubstituted indenes via a novel palladium-catalyzed cyclization reaction of propargylic carbonates with carbon nucleophiles [J] . Duan XH, Guo LN, Bi HP, Organic letters . 2006,第25期

机译：通过丙炔碳酸酯与碳亲核试剂的新型钯催化环化反应，高度区域选择性地合成2,3-二取代的茚
4. Synthesis of Allenes via Palladium-Catalyzed Hydrogen Transfer Reactions: Propargylic Amines As an Allenyl Anion Equivalent [C] . Hiroyuki Nakamura, Takaya Kamakura, Makoto Ishikura, Symposium on Organometallic Chemistry . 2004

机译：通过钯 - 催化的氢转移反应合成丙烯酯：丙基胺作为亚苯基阴离子等同物
5. Diastereoselective palladium-catalyzed formate reduction of allylic carbonates as a route to polypropionate systems. [D] . Chau, Anh. 2004

机译：非对映选择性钯催化的甲酸烯丙基碳酸盐的甲酸还原，这是通向聚丙烯酸酯体系的一种途径。
6. Regio- and diastereoselective reactions of chiral secondary alkylcopper reagents with propargylic phosphates: preparation of chiral allenes [O] . Juri Skotnitzki, Alexander Kremsmair, Daniel Keefer, 2020

机译：手性次级烷基磷盆试剂与磷酸丙氨酸丙氨酸的测定和非映选择反应：手性甲烷的制备
7. Palladium-Catalyzed Carboannulation of Propargylic Carbonates and Nucleophiles to 2-Substituted Indenes [O] . -1

机译：钯催化的碳酸酯和双替解茚的亲核试剂的碳泛船

Highly diastereoselective synthesis of tetrahydrobenzofuranones by palladium-catalyzed reaction of propargylic carbonates with 2-substituted cyclohexane-1,3-diones

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