Enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by a bis(oxazoline)-Cu(II) complex

Pradeep K.Singh; Alakesh Bisai; Vinod K.Singh

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Enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by a bis(oxazoline)-Cu(II) complex

机译：双（恶唑啉）-Cu（II）配合物催化硝基苯与吲哚的对映选择性Friedel-Crafts烷基化反应

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The catalytic enantioselective Friedel-Crafts reaction of indole with trans-beta-nitrostyrene is reported in the presence of copper triflate-bisoxazoline complexes.The reaction furnished nitroalkylated indoles in excellent yields (up to 95%) and high enantio-selectivities up to an 86% ee.

机译：据报道，在三氟甲磺酸铜-双恶唑啉配合物的存在下，吲哚与反式-β-硝基苯乙烯的催化对映选择性Friedel-Crafts反应提供了硝基烷基化的吲哚，收率高达95％，对映选择性高达86。％ee。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry 》 |2007年第7期| 共3页
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Pradeep K.Singh; Alakesh Bisai; Vinod K.Singh;
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1. Enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by a bis(oxazoline)-Cu(II) complex [J] . Pradeep K.Singh, Alakesh Bisai, Vinod K.Singh Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2007 ,第7期

机译：双（恶唑啉）-Cu（II）配合物催化硝基苯与吲哚的对映选择性Friedel-Crafts烷基化反应
2. Enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by bifunctional tridentate bis(oxazoline)-Zn(II) complex [J] . Lu SF, Du DM, Xu JX Organic letters . 2006 ,第10期

机译：双官能三齿双（恶唑啉）-Zn（II）配合物催化的硝基苯与吲哚的对映选择性弗里德-克来夫斯烷基化反应
3. Chiral Bis(Oxazolinyl)thiophenes for Enantioselective Cu(II)-Catalyzed Friedel-Crafts Alkylation of Indole Derivatives with Nitroalkenes [J] . Weijie Li Catalysis Letters . 2014 ,第5期

机译：手性双（恶唑啉基）噻吩用于对映体铜（II）催化的吲哚衍生物与硝基烯烃的Friedel-Crafts烷基化
4. Enantioselective Friedel-Crafts Alkylation Reaction of Indoles with Non-activated β-Alkyl-β-Nitrostyrenes Catalyzed by Chiral BINOL Phosphates [C] . Mio Kaneko, Ignacio Ibanez Sanchez, Takahiko Akiyama 日本化学会春季年会講演予稿集 . 2018

机译：用手性甲醇磷酸盐催化的非活化β-烷基-β-硝化吲哚的对映选择性的Friedel-Crafts抗体的烷基化反应
5. Asymmetric Friedel-Crafts alkylations catalyzed by bis(oxazolinyl)pyridine-scandium(III) triflate complexes. [D] . Fandrick, Keith Richard. 2007

机译：双（恶唑啉基）吡啶-三氟甲磺酸scan（III）催化的不对称Friedel-Crafts烷基化反应。
6. Spiro Indane-Based Phosphine-Oxazolines as Highly Efficient PN Ligands for Enantioselective Pd-Catalyzed Allylic Alkylation of Indoles and Allylic Etherification [O] . Zhongxuan Qiu, Rui Sun, Kun Yang, 2019

机译：基于螺茚满的膦-恶唑啉作为高效PN配体用于对映选择性Pd催化的吲哚烯丙基烷基化和烯丙基醚化
7. Enantioselective Friedel-Crafts Alkylation of Indoles with Nitroalkenes Catalyzed by Bifunctional Tridentate Bis(oxazoline)-Zn(II) Complex [O] . -1

机译：通过双官能三齿双（恶唑啉）-ZN（II）复合物催化催化吲哚酮糖的抗映射抗吲哚

Enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by a bis(oxazoline)-Cu(II) complex

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