An efficient solvent free catalytic oxidation of sulfides to sulfoxides with hydrogen peroxide catalyzed by a binaphthyl-bridged Schiff base titanium complex

De Rosa M; Lamberti M; Pellecchia C; Scettri A; Villano R; Soriente A

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >An efficient solvent free catalytic oxidation of sulfides to sulfoxides with hydrogen peroxide catalyzed by a binaphthyl-bridged Schiff base titanium complex

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An efficient solvent free catalytic oxidation of sulfides to sulfoxides with hydrogen peroxide catalyzed by a binaphthyl-bridged Schiff base titanium complex

机译：联萘桥联席夫碱钛配合物催化的过氧化氢将硫化物有效地无溶剂催化氧化为亚砜

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摘要

A titanium binaphthyl-bridged Schiff base complex proved to be an efficient catalyst for the hydrogen peroxide oxidation of aromatic and aliphatic sulfides to the corresponding sulfoxides in satisfactory yields under solvent-free conditions. (c) 2006 Elsevier Ltd. All rights reserved.

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2006年第40期|共3页
作者
De Rosa M; Lamberti M; Pellecchia C; Scettri A; Villano R; Soriente A;
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正文语种 eng
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salen ligands; Ti(IV) complexes; sulfoxidation; hydrogen peroxide; sulfoxide; oxidation; SELECTIVE OXIDATION; ASYMMETRIC OXIDATION; ORGANIC-SYNTHESIS; VANADIUM COMPLEX; SILICA-GEL; SULFONES; H2O2; DICHLOROMETHANE; FACILE; SYSTEM;

机译：Salen配体;Ti（IV）配合物;亚砜氧化;过氧化氢;亚砜;氧化;选择性氧化;不对称氧化;有机合成;钒配合物;硅胶-凝胶;砜;H2O2;二氯乙烷;颗粒;体系;

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1. An efficient solvent free catalytic oxidation of sulfides to sulfoxides with hydrogen peroxide catalyzed by a binaphthyl-bridged Schiff base titanium complex [J] . De Rosa M, Lamberti M, Pellecchia C, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2006,第40期

机译：联萘桥联席夫碱钛配合物催化的过氧化氢将硫化物有效地无溶剂催化氧化为亚砜
2. Metal-Free Chemoselective Oxidation of Sulfides to Sulfoxides by Hydrogen Peroxide Catalyzed by in situ Generated Dodecyl Hydrogen Sulfate in the Absence of Organic Co-Solvents [J] . H.Firouzabadi, N.Iranpoor, A.A.Jafari, Advanced synthesis & catalysis . 2006,第4a5期

机译：在没有有机助溶剂的情况下，原位生成的十二烷基硫酸氢盐催化过氧化氢将硫化物无金属化学选择性氧化为亚砜。
3. Uronium Hydrogen Sulfate/Urea-Hydrogen Peroxide as a Green and Metal-Free Catalytic System for the Efficient, Chemo-, and Homoselective Oxidation of Sulfides to Sulfoxides [J] . Alireza Hasaninejada Gholamabbas Chehardolib Mohammad Ali Zolfigolc amp, Abbas Abdolic Phosphorus, Sulfur, and Silicon and the Related Elements . 2011,第2期

机译：硫酸氢铀/过氧化氢脲作为绿色，无金属的催化体系，可将硫化物高效，化学和均质氧化为亚砜。
4. Mediated Improvement in Catalytic Performance of MCM-41 Immobilized Chromium Schiff Base Complex for Solvent-Free Oxidation of Cyclohexanol [C] . Xiaoli Wang, Gongde Wu, Fang Wang CEAM 2012 . 2012

机译：MCM-41固定化铬席夫碱基络合物催化性能的介导改善环己醇无溶剂氧化
5. Kinetics and mechanisms of the oxidation of alcohols and hydroxylamines by hydrogen peroxide, catalyzed by methyltrioxorhenium, MTO, and the oxygen binding properties of cobalt Schiff base complexes. [D] . Zauche, Timothy Harlan. 1998

机译：甲基三氧合hen，MTO催化过氧化氢氧化醇和羟胺的动力学和机理，以及钴席夫碱配合物的氧结合性能。
6. Effective Oxidation of Sulfides to Sulfoxides with Hydrogen Peroxide under Transition-Metal-Free Conditions [O] . Hamid Golchoubian, Farideh Hosseinpoor 2007

机译：在无过渡金属的条件下用过氧化氢将硫化物有效氧化为亚砜
7. Molybdatophosphoric acid as an efficient catalyst for the catalytic and chemoselective oxidation of sulfides to sulfoxides using urea hydrogen peroxide as a commercially available oxidant [O] . ALIREZA HASANINEJAD, MOHAMMAD ALI ZOLFIGOL, GHOLAMABBAS CHEHARDOLI, 2010

机译：使用尿素过氧化氢作为市售氧化剂，钼膦酸作为催化剂和催化剂选择性氧化硫化物成亚砜的有效催化剂
8. Adsorption and Catalytic Oxidation with Hydrogen Peroxide of Sulfide and ThioateSubstrates [R] . Drago, R. S. 1996

机译：硫化氢和硫代硫酸盐对过氧化氢的吸附和催化氧化

An efficient solvent free catalytic oxidation of sulfides to sulfoxides with hydrogen peroxide catalyzed by a binaphthyl-bridged Schiff base titanium complex

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