Skeletal rearrangements of bicyclo[2.2.2]lactones:a short and efficient route towards Corey's lactone

Benoit Augustyns; Nuno Maulide; Istvan E.Marko

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >Skeletal rearrangements of bicyclo[2.2.2]lactones:a short and efficient route towards Corey's lactone

【24h】

Skeletal rearrangements of bicyclo[2.2.2]lactones:a short and efficient route towards Corey's lactone

机译：双环[2.2.2]内酯的骨架重排：一条通往科里内酯的短而有效的途径

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

团队文献服务 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The application of a unique tandem radical-initiated,Bronsted acid-catalysed,skeletal rearrangement of bicyclo[2.2.2]-lactones provides a novel route towards Corey's lactone 2.The strategy also features a high-pressure promoted inverse electron-demand Diels-Alder (IEDDA) reaction of 3-carbomethoxy-2-pyrone (3-CMP),which proceeds with complete regio- and diastereocontrol.

机译：独特的串联自由基引发的布朗斯台德酸催化的双环[2.2.2]-内酯的骨架重排提供了通往科里内酯2的新途径。该策略还具有高压促进的反向电子需求Diels- 3-碳甲氧基-2-吡喃酮（3-CMP）的Alder（IEDDA）反应，可进行完全的区域和非对映控制。

著录项

来源
《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry 》 |2005年第22期| 共5页
作者
Benoit Augustyns; Nuno Maulide; Istvan E.Marko;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
Lactones; Bicyclic; Radical; Rearrangement; Corey's lactone; 3-CMP; Diels-Alder.;

机译：内酯;双环;自由基;重排;科里内酯;3-CMP;Diels-Alder;

相似文献

外文文献
中文文献
专利

1. Skeletal rearrangements of bicyclo[2.2.2]lactones:a short and efficient route towards Corey's lactone [J] . Benoit Augustyns, Nuno Maulide, Istvan E.Marko Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2005 ,第22期

机译：双环[2.2.2]内酯的骨架重排：一条通往科里内酯的短而有效的途径
2. Tandem radical rearrangement/Pd-catalysed translocation of bicyclo[2.2.2]lactones. An efficient access to the oxa-triquinane core structure [J] . Liao JH, Maulide N, Augustyns B, Organic & biomolecular chemistry . 2006 ,第8期

机译：双环[2.2.2]内酯的串联自由基重排/ Pd催化易位。有效获得氧杂-三喹烷核心结构
3. Synthesis of b,c-disubstituted-c-lactones through a Johnson–Claisen rearrangement: a short route to xylobovide, nor-anadensolide, canadensolide, sporothriolide and santolinolide [J] . Rodney A. Fernandes, Arun B. Ingle, Vijay P. Chavan Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2010 ,第24期

机译：通过Johnson-Claisen重排合成b，c-二取代-c-内酯：制备xylobovide，nor-anadensolide，canadensolide，sporothriolide和santolinolide的捷径
4. One-pot synthesis of Corey lactone in 150-minutes and totalsynthesis of latanoprost [C] . Nariyoshi Umekubo, Yujiro Hayashi 日本化学会春季年会 . 2020

机译：150分钟内核心内酯的一锅合成，拉坦斯普洛斯特的Totalsynthesis
5. I. BRIDGED TRANS-CYCLOHEPTENES: BICYCLO(3.2.2)NON-1-ENE, BICYCLO(3.2.2)NON-1(7)-ENE, BICYCLO(3.2.1)OCT-1-ENE, AND BICYCLO(3.2.1)OCT-1(7)-ENE. II. NEOPENYL REARRANGEMENTS: THE INTERCONVERSIONS OF BICYCLO(3.2.2)NON-1-YL, BICYCLO(3.2.1)-OCTANE-1-METHYL, AND BICYCLO(2.2.2)OCTANE-1-METHYL SYSTEMS. [D] . CHONG, JOSHUA ANTHONY. 1971

机译：I.桥接跨环蛋白：双环（3.2.2）NON-1-ENE，双环（3.2.2）NON-1（7）-ENE，双环（3.2.1）OCT-1-ENE和双环（3.2） .1）OCT-1（7）-ENE。二。新戊基重排：Bicyclo（3.2.2）NON-1-YL，BICYCLO（3.2.1）-OCTANE-1-甲基和BICYCLO（2.2.2）OCTANE-1-甲基系统的互换。
6. Pot and time economies in the total synthesis of Corey lactone [O] . Nariyoshi Umekubo, Yurina Suga, Yujiro Hayashi 2020

机译：Corey内酯的总合成锅和时间经济
7. Synthesis of some bicyclo2.2.2oct-5-en-2-ones and bicyclo2.2.2octan-2-ones. Rearrangements accompanying oxidative decarboxylation with lead tetraacetate [O] . Peter Yates, Gordon E. Langford 1981

机译：一些双环的合成2.2.2 OCT-5-ZH-2- on anyclo 2.2.2辛烷-2-乙二醇。伴随氧化脱羧与铅四乙酸盐的重排

Skeletal rearrangements of bicyclo[2.2.2]lactones:a short and efficient route towards Corey's lactone

摘要

著录项

相似文献

相关主题

期刊订阅